α-Alkylation of ketones with primary alcohols by an active non-noble metal Cu/CuOx catalyst

Literature Information

Publication Date 2023-12-23
DOI 10.1039/D3OB01836A
Impact Factor 3.876
Authors

Hongli Wang, Chun-Ran Chang


View Original

Abstract

Development of convenient and effective heterogeneous non-noble metal catalysts for α-alkylation of ketones with alcohols is challenging in heterogeneous catalysis. Here, we report active non-noble metal Cu/CuOx catalysts for the construction of C–C bonds by the α-alkylation of ketones with alcohols through the borrowing hydrogen methodology. The optimal Cu/CuOx-250 catalyst exhibits good catalytic performance in the reactions to give the corresponding products in 50–96% yields. The Cu/CuOx catalysts are characterized by different analysis techniques such as XRD, TEM, XPS, H2-TPR, BET, and ICP. Moreover, the catalyst can be reused at least for five successive cycles without significant loss of activity. The present study provides meaningful insights into the development of non-noble metal heterogeneous catalysts for α-alkylation of ketones with alcohols.

Related Literature

A facile preparation of PEO–LiClO4–fumed SiO2 composite solid-state electrolyte with improved electrochemical performance for lithium-metal batteries

Ruyan Lei, Yanping Yang, Chenjuan Yu, Yinsi Xu, Yuanzhuo Li, Jun Li

2021-01-28 Paper

DOI: 10.1039/D1SE00038A

New approaches in component design for dye-sensitized solar cells

Nick Vlachopoulos, Anders Hagfeldt, Guobin Jia, Ruri Agung Wahyuono, Jonathan Plentz, Benjamin Dietzek

2020-11-16 Perspective

DOI: 10.1039/D0SE00596G

Crystal size-controlled growth of bismuth vanadate for highly efficient solar water oxidation

Qi Qin, Qian Cai, Wei Liu

2021-01-08 Paper

DOI: 10.1039/D0SE01642J

Nb2C MXene assisted CoNi bimetallic catalysts for hydrogenolysis of aromatic ethers

Sen-Wang Wang, Zhen-Hong He, Jian-Gang Chen, Kuan Wang, Zhong-Yu Wang, Pan-Pan Guo, Jie Lan, Weitao Wang

2020-12-28 Paper

DOI: 10.1039/D0SE01532F

Front cover

2021-02-23 Cover

DOI: 10.1039/D1SE90013G

Nitrogen-doped graphene/graphitic carbon nitride with enhanced charge separation and two-electron-transferring reaction activity for boosting photocatalytic hydrogen peroxide production

Muye Liu, Yue Wen, Luhua Lu, Ying Chen, Xiaocong Tian, Hongyun Jin, Jinghai Liu, Kai Dai

2021-02-03 Paper

DOI: 10.1039/D0SE01828G

A hierarchical CoP@NiCo-LDH nanoarray as an efficient and flexible catalyst electrode for the alkaline oxygen evolution reaction

Wenli Tian, Jie Zhang, Hao Feng, Hao Wen, Xun Sun, Xin Guan, Dengchao Zheng, Jing Liao, Minglei Yan, Yadong Yao

2020-11-23 Communication

DOI: 10.1039/D0SE01490G

Insights into the phenomenon of ‘bubble-free’ electrocatalytic oxygen evolution from water

Richard Terrett, Zheyin Yu, Zhenxiang Cheng, Gerhard F. Swiegers, Takuya Tsuzuki, Robert Stranger, Ronald J. Pace

2020-12-21 Paper

DOI: 10.1039/D0SE01633K

You might also like

Compound Q&A

What regulatory guidelines apply to 4-Amino-3-bromophenol (CAS: 74440-80-5)?

4-Amino-3-bromophenol (CAS: 74440-80-5) falls under the classification of a haza...

74440-80-54-Amino-3-bromopheno...
Compound Q&A

How should (17beta)-3-Oxoestr-4-en-17-yl acetate (CAS: 1425-10-1) be stored?

(17beta)-3-Oxoestr-4-en-17-yl acetate should be stored in a cool, dry place away...

1425-10-1(17beta)-3-Oxoestr-4...
Compound Q&A

What are the physical and chemical properties of 2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0)?

2-[(2,2-Diethoxyethyl)disulfanyl]-1,1-diethoxyethane (CAS: 76505-71-0) is a colo...

76505-71-02-[(2,2-Diethoxyethy...
Compound Q&A

What is the market or research trend for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-amine?

The market and research for 1-(β-D-ribofuranosyl)-1H-imidazo[4,5-c]pyridin-4-ami...

6736-58-91-(beta-D-Ribofurano...
Compound Q&A

How should waste containing Conjugated Estrogen (CAS: 12126-59-9) be handled?

Waste containing Conjugated Estrogen (CAS: 12126-59-9) should be collected and d...

12126-59-9Conjugated Estrogen
Compound Q&A

What is the market or research trend for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate?

The market for Bis(2,2,2-trifluoroethyl) (methoxycarbonylmethyl)phosphonate (CAS...

88738-78-7Bis(2,2,2-trifluoroe...
Compound Q&A

Are there alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9) in synthesis?

There are several alternatives to 3,4'-Di-O-methylellagic acid (CAS: 57499-59-9)...

57499-59-93,4'-Di-O-methylella...
Compound Q&A

What regulatory guidelines apply to 2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0)?

2-Chloro-N,N-dimethylpyridin-4-amine (CAS: 59047-70-0) is regulated under the Gl...

59047-70-02-Chloro-N,N-dimethy...
Compound Q&A

What is cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8)?

Cerium(3+);oxygen(2-);vanadium(5+) (CAS: 13597-19-8) is a complex inorganic comp...

13597-19-8cerium(3+);oxygen(2-...
Compound Q&A

Is 7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) safe?

7-Chloro-1-iodoisoquinoline (CAS: 1203579-27-4) is generally considered safe whe...

1203579-27-47-Chloro-1-iodoisoqu...

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.