Molecular specificity in neutron imaging: the case of hydrogen adsorption in metal organic frameworks

Literature Information

Publication Date 2023-11-02
DOI 10.1039/D3CP04176J
Impact Factor 3.676
Authors

Margherita Simoni, Triestino Minniti


View Original

Abstract

Neutron imaging is the technique of choice for a number of in situ and operando applications, where a high penetration power is required. White-beam neutron imaging and energy-resolved Bragg edge imaging are successful techniques, the former for the detection of specific elements characterized by strong neutron attenuation and the latter for studying crystal structures. Here we discuss the capabilities of energy-selective neutron imaging taking advantage of the incoherent and inelastic scattering interactions in hydrogenous materials, as a way to obtain molecular-specific information about the composition of a given sample. While few examples from the available literature are discussed, a worked example is presented based on new experimental data on molecular-hydrogen adsorption and conversion in the HKUST-1 metal organic framework.

Related Literature

Defocused dark-field orientation imaging of single gold microrods on synthetic membranes

Junho Lee, Ji Won Ha

2017-08-22 Communication

DOI: 10.1039/C7CP04714B

Electrochemical properties of an aluminum anode in an ionic liquid electrolyte for rechargeable aluminum-ion batteries

Sangwon Choi, Hyungho Go, Gibaek Lee, Yongsug Tak

2017-01-25 Communication

DOI: 10.1039/C6CP08776K

Performance limitations in thieno[3,4-c]pyrrole-4,6-dione-based polymer:ITIC solar cells

Deping Qian, Ahmed Hesham Balawi, Yang Wu, Wei Ma, Frédéric Laquai, Zheng Tang, Fengling Zhang, Weiwei Li

2017-08-15 Paper

DOI: 10.1039/C7CP04780K

Nuclear dynamics and phase polymorphism in solid formic acid

Kacper Drużbicki, Giovanni Romanelli, Matthias J. Gutmann, Svemir Rudić, Silvia Imberti

2017-03-13 Paper

DOI: 10.1039/C7CP00997F

Less stable tautomers form stronger hydrogen bonds: the case of water complexes

Shmuel Zilberg, Bernhard Dick

2017-09-01 Paper

DOI: 10.1039/C7CP04105E

Anharmonic vibrational effects in linear and two-dimensional electronic spectra

Arpa Galestian Pour, Craig Norman Lincoln, Václav Perlík, František Šanda, Jürgen Hauer

2017-08-25 Paper

DOI: 10.1039/C7CP05189A

Theoretical and experimental examination of SFG polarization analysis at acetonitrile–water solution surfaces

Kengo Saito, Qiling Peng, Lin Qiao, Tatsuya Joutsuka, Tatsuya Ishiyama

2017-03-03 Paper

DOI: 10.1039/C6CP08856B

The oxidation kinetics of thin nickel films between 250 and 500 °C

Y. Unutulmazsoy, R. Merkle, D. Fischer, J. Mannhart, J. Maier

2017-03-17 Paper

DOI: 10.1039/C7CP00476A

You might also like

Compound Q&A

How should 2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) be stored?

2-Methylbenzene-1,4-diamine dihydrochloride (CAS: 615-45-2) should be stored in ...

615-45-22-Methylbenzene-1,4-...
Compound Q&A

Is (1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide (CAS: 132747-20-7) safe?

(1S,4S)-2,5-Diazabicyclo[2.2.1]heptane dihydrobromide is generally considered sa...

132747-20-7(1S,4S)-2,5-Diazabic...
Compound Q&A

What industries use (6-Chloropyridazin-3-YL)methanamine (CAS: 871826-15-2)?

(6-Chloropyridazin-3-YL)methanamine finds applications in the pharmaceutical ind...

871826-15-2(6-Chloropyridazin-3...
Compound Q&A

What are the main uses of 2-Fluoro-3-methylphenol (CAS: 77772-72-6)?

2-Fluoro-3-methylphenol is primarily used in the synthesis of pharmaceuticals, p...

77772-72-62-Fluoro-3-methylphe...
Compound Q&A

What precautions should be taken when handling 3-Methoxy-4-nitrobenzonitrile (CAS: 177476-75-4)?

When handling 3-Methoxy-4-nitrobenzonitrile, it is important to wear appropriate...

177476-75-43-Methoxy-4-nitroben...
Compound Q&A

What precautions should be taken when handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4)?

When handling 1,3-Oxazolo[4,5-b]pyridine-2(3H)-thione (CAS: 211949-57-4), it is ...

211949-57-4[1,3]Oxazolo[4,5-b]p...
Compound Q&A

What regulatory guidelines apply to 4-Ethynylbenzamide (CAS: 90347-86-7)?

4-Ethynylbenzamide (CAS: 90347-86-7) falls under various regulatory guidelines i...

90347-86-74-Ethynylbenzamide
Compound Q&A

What are the main uses of 3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone (CAS: 186822-57-1)?

3-(2-Ethylphenyl)-2-thioxo-4-imidazolidinone is primarily used as an intermediat...

186822-57-13-(2-Ethylphenyl)-2-...
Compound Q&A

What is (2-Fluoro-6-methoxyphenyl)acetic acid (CAS: 500912-19-6)?

(2-Fluoro-6-methoxyphenyl)acetic acid, also known as 4-fluoro-3-methoxybenzoic a...

500912-19-6(2-Fluoro-6-methoxyp...
Compound Q&A

What is the market or research trend for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9)?

Market trends for 2-[4-(Hydroxymethyl)phenoxy]ethanol (CAS: 102196-18-9) indicat...

102196-18-92-[4-(Hydroxymethyl)...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.