The behaviour of tricyclic fused host systems comprising seven-membered B-rings in mixed pyridines
Literature Information
Benita Barton, Mino R. Caira, Danica B. Trollip, Eric C. Hosten
In this work, the selectivity behaviour of two tricyclic fused host systems with seven-membered B-rings, namely N,N′-bis(5-phenyl-5-dibenzo[a,d]cycloheptenyl)ethylenediamine (H1) and N,N′-bis(5-phenyl-10,11-dihydro-5-dibenzo[a,d]cycloheptenyl)ethylenediamine (H2), was investigated in various mixtures of pyridine (PYR) and the three C-methylated pyridine isomers (2-, 3-, and 4-MP). It was first demonstrated that H1 possessed the ability to enclathrate all four pyridines in the single guest solvent experiments while H2 was only able to form complexes with PYR and 4MP. H2 showed significantly enhanced selectivities compared with H1, consistently preferring PYR, while 2MP was the favoured guest of H1. Selectivity profiles suggested that H1 has the ability to separate mixtures of 2MP/PYR when these contain 40% 2MP (K = 11.8). H2, on the other hand, was shown to have exceptional separatory potential for PYR/2MP and PYR/3MP mixtures even when the amount of PYR in these was as low as 20%. These host compounds, therefore, are able to separate some of these pyridyl mixtures with high efficiency. SCXRD analyses on five of the six complexes prepared here demonstrated that the reason for the preferential behaviours of H1 and H2 for 2MP and PYR, respectively, was the significantly shorter hydrogen bonding interactions present between the host and guest molecules in these complexes. Thermal analyses further showed that these two complexes were more thermally stable than those with the less preferred guest compounds.
Recommended Journals
Related Literature
Growth of axial nested P–N heterojunction nanowires for high performance diodes
Nan Chen, Zheng Xue, Hui Yang, Zhou Zhang, Juan Gao, Yongjun Li, Huibiao Liu
DOI: 10.1039/C4CP04397A
The planar electric double layer capacitance for the solvent primitive model electrolyte
Stanisław Lamperski, Monika Płuciennik, Christopher W. Outhwaite
DOI: 10.1039/C4CP03513E
Electronic structure aspects of the complete O2 transfer reaction between Ni(ii) and Mn(ii) complexes with cyclam ligands
Jhon Zapata-Rivera, Rosa Caballol, Carmen J. Calzado
DOI: 10.1039/C4CP05127K
Nano-design of quantum dot-based photocatalysts for hydrogen generation using advanced surface molecular chemistry
Dalal Noureldine, Tayirjan Isimjan, Bin Lin, Silvano Del Gobbo, Mutalifu Abulikemu, Mohamed Nejib Hedhili, Dalaver H. Anjum, Kazuhiro Takanabe
DOI: 10.1039/C4CP04365K
Energetic contributions of residues to the formation of early amyloid-β oligomers
R. Pouplana, J. M. Campanera
DOI: 10.1039/C4CP04544K
Oxygen vacancy and hole conduction in amorphous TiO2
Hieu H. Pham, Lin-Wang Wang
DOI: 10.1039/C4CP04209C
Intermediates caught in the act: tracing insulin amyloid fibril formation in time by combined optical spectroscopy, light scattering, mass spectrometry and microscopy
A. Gladytz, T. Häupl, K. R. Siefermann
DOI: 10.1039/C4CP03072A
Whirl-enhanced continuous wave laser trapping of particles‡
S. Bartkiewicz, A. Miniewicz
DOI: 10.1039/C4CP04008B
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
CrystEngComm

CrystEngComm is the forum for the design and understanding of crystalline materials. We welcome studies on the investigation of molecular behaviour within crystals, control of nucleation and crystal growth, engineering of crystal structures, and construction of crystalline materials with tuneable properties and functions. We publish hypothesis-driven research into… how crystal design affects thermodynamics, phase transitional behaviours, polymorphism, morphology control, solid state reactivity (crystal-crystal solution-crystal, and gas-crystal reactions), optoelectronics, ferroelectric materials, non-linear optics, molecular and bulk magnetism, conductivity and quantum computing, catalysis, absorption and desorption, and mechanical properties. Using Techniques and methods including… Single crystal and powder X-ray, electron, and neutron diffraction, solid-state spectroscopy, spectrometry, and microscopy, modelling and data mining, and empirical, semi-empirical and ab-initio theoretical evaluations. On crystalline and solid-state materials. We particularly welcome work on MOFs, coordination polymers, nanocrystals, host-guest and multi-component molecular materials. We also accept work on peptides and liquid crystals. All papers should involve the use or development of a design or optimisation strategy. Routine structural reports or crystal morphology descriptions, even when combined with an analysis of properties or potential applications, are generally considered to be outside the scope of the journal and are unlikely to be accepted.










![2-Bromodibenzo[b,d]furan structure 2-Bromodibenzo[b,d]furan structure](https://static.chemtradehub.com/structs/86-/86-76-0-1814.webp)
![1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure 1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure](https://static.chemtradehub.com/structs/192/19210-12-9-ecae.webp)


