Photoinduced fluorescence modulation through controllable intramolecular [2+2] photocycloaddition in single molecules and molecular aggregates
Literature Information
Publication Date
2024-01-02
DOI
10.1039/D3CC05846H
Impact Factor
6.222
Authors
Yuzhen Wu, Xinni Ping, Chuangye Yao, Penglei Wu, Zhengdong Han, Xin Peng, Jiale Zhan, Hui Feng, Zhaosheng Qian
View Original
Abstract
We report a general molecular design strategy of spatial proximity, which allows intramolecular [2+2] photocycloaddition reaction to take place in both single molecules and molecular aggregates. Sharply contrasting photoinduced fluorescence changes in solution and in the solid state were found and attributed to the aggregation-induced quenching property of the monomers and the aggregation-induced emission nature of the photodimers.
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Source Journal
Chemical Communications
CiteScore:
8.6
Self-citation Rate:
4.7%
Articles per Year:
2458
ChemComm publishes urgent research which is of outstanding significance and interest to experts in the field, while also appealing to the journal’s broad chemistry readership. Our communication format is ideally suited to short, urgent studies that are of such importance that they require accelerated publication. Our scope covers all topics in chemistry, and research at the interface of chemistry and other disciplines (such as materials science, nanoscience, physics, engineering and biology) where there is a significant novelty in the chemistry aspects. Major topic areas covered include: Analytical Chemistry Catalysis Chemical Biology and medicinal chemistry Computational Chemistry and Machine Learning Energy and sustainable chemistry Environmental Chemistry Green Chemistry Inorganic Chemistry Materials Chemistry Nanoscience Organic Chemistry Physical Chemistry Polymer Chemistry Supramolecular Chemistry
Recommended Compounds
![(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure](https://static.chemtradehub.com/structs/102/10293-06-8-dd8a.webp "(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one structure")
(1R)-3-Bromo-1,7,7-trimethylbicyclo[2.2.1]heptan-2-one
CAS Number:
10293-06-8
Molecular Formula:
C10H15BrO
5,7-Dihydroxy-2-(4-hydroxyphenyl)-4-oxo-4H-chromen-3-yl 2-O-(6-deoxy-alpha-L-mannopyranosyl)-beta-D-glucopyranoside
CAS Number:
32602-81-6
Molecular Formula:
C27H30O15
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