Engineering a defect-rich Prussian blue analog composite for enhanced Cs+ removal performance

Literature Information

Publication Date 2023-11-29
DOI 10.1039/D3CC05170F
Impact Factor 6.222
Authors

Zhenwei Wei, Weilian Zhao, Jiayin Hu, Tianlong Deng, Nan Zhang


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Abstract

Using a novel, irregular honeycombed N-doped porous carbon (NPC) as a support and defect inducer, defect-rich Zn–PBA was formed in situ and evenly anchored on the surface of NPC to obtain a defect-rich Zn–PBA/NPC composite. This composite demonstrated an ultrafast Cs+ adsorption rate that reached equilibrium within 60 s as well as excellent adsorption capacity, stability and reusability. The adsorption mechanism indicated that Cs+ was quickly adsorbed via the defect sites close to the Zn–PBA crystal face accompanied by K(OH2)+ elimination.

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