Resonance and structural assignment in (car)borane clusters using 11B residual quadrupolar couplings

Literature Information

Publication Date 2023-11-22
DOI 10.1039/D3CC05054H
Impact Factor 6.222
Authors

Franziska Rüttger, Dietmar Stalke, Michael John


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Abstract

A new NMR method for structural verification and 11B resonance assignment in (car)borane clusters is presented, based on the measurement of 11B residual quadrupolar couplings (RQCs) in a stretched polystyrene (PS) gel. The method was applied to ortho-carborane (B10C2H12), a derivative thereof with reduced symmetry, meta-carborane and decaborane (B10H14).

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