Phytic acid cross-linked and Hofmeister effect strengthened polyvinyl alcohol hydrogels for zinc ion storage

Literature Information

Publication Date 2023-12-06
DOI 10.1039/D3CC05008D
Impact Factor 6.222
Authors

Haiou Wang, Yingqi Hu, Zhan Wang, Yingzhi Li, Weimin Yang, Hua Cheng, Zhouguang Lu


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Abstract

It is a big challenge to retain the water and thus reduce the charge impedance for solid electrolytes used in flexible and wearable zinc ion batteries. Here, we propose novel phytic acid (PA) cross-linked polyvinyl alcohol (PVA) hydrogels as high-performanced solid electrolytes strengthened by the Hofmeister effect. In this approach, freeze-thawing followed by a salting-out procedure via anions to induce the Hofmeister effect can greatly improve the tensile strain and flexibility of the hydrogels. The PA addition dramatically enhances the ionic conductivity and increases the affinity between the electrolyte and zinc plate. Consequently, the PVA/PA hydrogels exhibit remarkable electrochemical performances with stable full-cell cycling in zinc ion storage and capability in inhibiting Zn dendrite growth.

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