Development of 3-triazenylaryne and its application to iterative aryne reactions via o-triazenylarylboronic acids

Literature Information

Publication Date 2023-11-02
DOI 10.1039/D3CC04878K
Impact Factor 6.222
Authors

Motoki Ito, Yuta Takishima, Rinto Ishikawa, Mao Kamimura, Hana Watanabe, Takehiro Konishi, Kazuhiro Higuchi, Shigeo Sugiyama


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Abstract

Herein, a novel aryne species, 3-triazenylaryne, was developed and its regioselectivity was revealed. Based on the regioselectivity, various alkyne moieties were introduced by iodoalkynylation, and further derivatization to o-triazenylarylboronic acids as 3-alkynylaryne precursors was enabled. Therefore, 3-triazenylaryne was developed as a divergent platform for the generation of various 3-alkynylarynes.

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