In situ rapid synthesis of ionic liquid/ionic covalent organic framework composites for CO2 fixation

Literature Information

Publication Date 2023-11-13
DOI 10.1039/D3CC04763F
Impact Factor 6.222
Authors

Zhifeng Xu, Wenting Wang, Bowei Chen, Haitao Zhou, Qiufang Yao, Xianjie Shen, Yuchen Pan, Dongxian Wu, Yongyong Cao, Zhangfeng Shen, Yanan Liu, Qineng Xia, Xi Li, Xiaoqin Zou, Yangang Wang, Lingchang Jiang


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Abstract

IL/ICOF composites were in situ synthesized via a one-pot route in half an hour under ambient conditions for catalytic cycloaddition of CO2 with epoxides into cyclic carbonates. The prepared composites feature a decent CO2 adsorption capacity of 1.63 mmol g−1 at 273 K and 1 bar and exhibit excellent catalytic performance in terms of yield and durability. This work may pave a new way to design and construct functionalized porous organic frameworks as heterogeneous catalysts for CO2 capture and conversion.

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