Fluorophosphoniums as Lewis acids in organometallic catalysis: application to the carbonylation of β-lactones‡

Literature Information

Publication Date 2024-01-04
DOI 10.1039/D3CC04282K
Impact Factor 6.222
Authors

Marie-Hélène Pietraru, Louise Ponsard, Nicolas Lentz, Pierre Thuéry, Emmanuel Nicolas, Thibault Cantat


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Abstract

We describe the synthesis and characterisation of four organic Lewis acids based on fluorophosphoniums, with tetracarbonyl cobaltate as the counter-anion: [R3PF]+[Co(CO)4]− (with R = o-Tol, Cy, iPr, and tBu). Their catalytic activity was investigated for the carbonylation of β-lactones to succinic anhydrides. In the presence of [tBu3PF]+[Co(CO)4]− IV (3 mol%), 90% of succinic anhydride was afforded from β-propiolactone after 16 h at 80 °C, at a very mild pressure of 2 bar of carbon monoxide. Our study sets the first example of the use of a main-group cation as a Lewis acidic partner in the cobalt-catalyzed carbonylation of β-lactones.

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Chemical Communications
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