Oxygenation of thiolates to S-bonded sulfinate in an iron(iii) complex related to nitrile hydratase

Literature Information

Publication Date 2003-12-16
DOI 10.1039/B312318A
Impact Factor 6.222
Authors

Erwan Galardon, Michel Giorgi, Isabelle Artaud


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Abstract

Air oxidation of the iron(III) complex derived from (2-mercaptoisobutyryl)-4,5-dichloro-o-phenylenediamine in the presence of Et4NCN afforded the corresponding disulfinato species. With two carboxamido nitrogens trans to two S-bonded sulfinates, this complex mimics the disulfinate inactive form of Fe-NHase.

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Chemical Communications

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