[Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6]: a mononuclear 16e− ruthenium(ii) catalyst for propargylic substitution and isomerization of HCCCPh2(OH)
Literature Information
Victorio Cadierno, Josefina Díez, Sergio E. García-Garrido, José Gimeno
The 16e− derivative [Ru(η3-2-C3H4Me)(CO)(dppf)][SbF6] catalyzes: (i) the propargylic substitution reaction of 1,1-diphenyl-2-propyn-1-ol with alcohols to produce propargylic ethers, and (ii) the formal isomerization of 1,1-diphenyl-2-propyn-1-ol into 3,3-diphenyl-2-propenal.
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