Influence of solvent on cyclic polynorbornene tacticity

Literature Information

Publication Date 2023-10-31
DOI 10.1039/D3CC04167K
Impact Factor 6.222
Authors

Sung-Min Hyun, Arkadios Marathianos, Ion Ghiviriga, Daniel W. Lester, Brent S. Sumerlin, Adam S. Veige


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Abstract

Tacticity is critical to polymer properties. The influence of solvent on tacticity in the catalytic synthesis of cyclic polynorbornene (c-PNB) is reported. In toluene cis,syndiotactic c-PNB forms; in THF, cis,syn/iso c-PNB forms.

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