Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet
Literature Information
Niki Mavragani, Alexandros A. Kitos, Diogo A. Gálico, Akseli Mansikkamäki, Muralee Murugesu
Reaction of the 1,2,4,5-tetrazine (tz˙−) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln–radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙−)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.
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