Probing the magnetic and magneto-optical properties of a radical-bridged Tb4 single-molecule magnet

Literature Information

Publication Date 2023-10-30
DOI 10.1039/D3CC03034B
Impact Factor 6.222
Authors

Niki Mavragani, Alexandros A. Kitos, Diogo A. Gálico, Akseli Mansikkamäki, Muralee Murugesu


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Abstract

Reaction of the 1,2,4,5-tetrazine (tz˙−) radical and {Cp*2Tb}+ has yielded a tetranuclear radical-bridged TbIII single-molecule magnet. The strong Ln–radical coupling and the electronic differences of the TbIII ions in [(Cp*2Tb)4(tz˙−)4]·3C6H6 (1) are probed via magnetic, magneto-optical and computational studies.

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