Commercially available palladium salts as practical and green single-component catalysts in the coordination polymerization of 1-chloro-2-phenylacetylenes in air
Literature Information
Jupeng Chen, Xiaolin Wu, Shaowen Zhang, Xiangqian Yan, Xiaolu Wu, Qingbin Cao, Huan Xu, Xiaofang Li
Commercially available palladium salts (1–4) (1: PdCl2; 2: PdCl2(CH3CN)2; 3: PdCl2(C6H5CN)2; and 4: Pd(OAc)2) served as low-cost, stable, green, broad-spectrum, and single-component catalysts with low sensitivity toward functional groups and solvents during the coordination polymerization of various 1-chloro-2-phenylacetylenes, Cl–CC–C6H4R (a–j), in air without a co-catalyst, providing a new metal catalyst design concept for the coordination polymerization of disubstituted alkynes.
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