Stereospecific recognition of a chiral centre over multiple flexible covalent bonds by 19F-NMR
Literature Information
Publication Date
2022-12-09
DOI
10.1039/D2AN01632J
Impact Factor
4.616
Authors
Ya-Ting Chen, Bin Li, Jia-Liang Chen, Xun-Cheng Su
View Original
Abstract
High performance in chiral recognition by a reactive 19F-tag was demonstrated for a variety of enantiomers. The analytes with up to five flexible covalent bonds from the chiral center can be discriminated by a sensitive chiral reporter manifested in the 19F-NMR spectrum. Simultaneous identification of chiral amines in a mixture and high accuracy ee determination were achieved.
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