Hydroamination of ethylene with NH3 induced by non-thermal atmospheric plasma
Literature Information
Julien Dieu, François Jérôme, Catherine Batiot-Dupeyrat
We show here that non-thermal atmospheric plasma induces the cleavage of the N–H bond of NH3 to form aminium radicals, which then add onto ethylene to form ethylamine in 17% yield. This technology can be also extended to n-octene, leading to the formation of 1-octylamine, i.e. with anti-Markovnikov addition of NH3.
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Reaction Chemistry & Engineering

Reaction Chemistry & Engineering is an interdisciplinary journal reporting cutting-edge research focused on enhancing the understanding and efficiency of reactions. Reaction engineering leverages the interface where fundamental molecular chemistry meets chemical engineering and technology. Challenges in chemistry can be overcome by the application of new technologies, while engineers may find improved solutions for process development from the latest developments in reaction chemistry. Reaction Chemistry & Engineering is a unique forum for researchers whose interests span the broad areas of chemical engineering and chemical sciences to come together in solving problems of importance to wider society. All papers should be written to be approachable by readers across the engineering and chemical sciences. Papers that consider multiple scales, from the laboratory up to and including plant scale, are particularly encouraged.










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