Photochemical CO2 reduction using structurally controlled g-C3N4

Literature Information

Publication Date 2016-08-18
DOI 10.1039/C6CP04525A
Impact Factor 3.676
Authors

James J. Walsh, Chaoran Jiang, Junwang Tang, Alexander J. Cowan


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Abstract

Graphitic carbon nitride (g-C3N4) synthesised from a urea precursor is an excellent CO2 reduction photocatalyst using [Co(bpy)n]2+ as a co-catalyst. A five-fold increase in activity for the highly polymerised urea derived g-C3N4 is achieved compared to alternative precursors. Transient absorption, time-resolved and steady-state emission studies indicate that the enhanced activity is related to both an increased driving force for photoelectron transfer and a greater availability of photogenerated charges.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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