Visible-light-promoted divergent functionalizations of methylenecyclopropanes
Literature Information
Publication Date
2021-09-09
DOI
10.1039/D1QO01187A
Impact Factor
5.281
Authors
Baoxiang Zhu, Zhao Wang, Hui Xi, Zengqiang Feng, Binglei Wang, Wenyang Jiao, Zhongxian Li, Zechao Wang, Junliang Wu
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Abstract
Simple and convenient visible-light-promoted radical monofunctionalization and difunctionalization of methylenecyclopropanes via ring-opening and cyclization processes have been developed for the syntheses of difluoromethyl compounds, alkyl compounds, halides, and sulfonyl compounds in moderate to excellent yields. The methodologies feature a wide substrate scope and tolerate various functional groups. A possible radical mechanism has been investigated and proven as a single electron transfer (SET) procedure.
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