A Catellani and retro-Diels–Alder strategy to access 1-amino phenanthrenes via ortho- and interannular C–H activation of 2-iodobiphenyls
Literature Information
Publication Date
2021-10-02
DOI
10.1039/D1QO01103K
Impact Factor
5.281
Authors
Mingjie Sun, Xinyang Chen, Zichao Feng, Guobo Deng, Yuan Yang, Yun Liang
View Original
Abstract
An efficient palladium-catalyzed three-component domino reaction of 2-iodobiphenyls, O-benzoylhydroxylamines, and norbornadiene has been developed to construct diverse 1-amino phenanthrene derivatives. The methodology realizes simultaneous construction of one C–N bond and two C–C bonds via a Catellani and retro-Diels–Alder strategy by ortho- and interannular C–H activation of 2-iodobiphenyls. Furthermore, this methodology features good functional group tolerance and broad substrate scope.
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Organic Chemistry Frontiers
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