Regio- and stereoselective cobalt-catalyzed hydrosilylation of 1,3-diynes with primary and secondary silanes
Literature Information
Publication Date
2021-09-15
DOI
10.1039/D1QO00939G
Impact Factor
5.281
Authors
Shaocong Shen, Zhijian Zong, Nan Sun, Baoxiang Hu, Zhenlu Shen, Xinquan Hu
View Original
Abstract
Reported herein is a well-defined geometry-constrained tridentate NNN-cobalt complex for regio- and stereoselective hydrosilylation of 1,3-diynes. Both primary and secondary silanes were suitable silylating reagents in this catalytic protocol. A wide range of symmetrical and unsymmetrical 1,3-diynes were tolerated to give diverse 1,3-enynylsilanes in moderate to excellent yields. The scale-up reaction demonstrated the practicality and efficiency of the developed strategy, as well as other further derivations of 1,3-enynylsilanes.
Recommended Journals
Russian Chemical Reviews
Pharmacological Reviews
Journal of Catalysis
Fibre Chemistry
Journal of Physics and Chemistry of Solids
Molecular Pharmacology
Proceedings of the National Academy of Sciences of the United States of America
Nature
Organic Preparations and Procedures International
Journal of Medicinal Chemistry
Related Literature
Introducing mesoscopic charge transfer rates into molecular electronics
Adriano Santos, Ushula M. Tefashe, Richard L. McCreery, Paulo R. Bueno
2020-04-27
Communication
DOI: 10.1039/D0CP01621G
Wetting state transition of a liquid gallium drop at the nanoscale
Meng Yan, Tao Li, Peiru Zheng, Rubin Wei, Yanyan Jiang, Hui Li
2020-04-21
Paper
DOI: 10.1039/D0CP00985G
Fine structure in the solution state 13C-NMR spectrum of C60 and its endofullerene derivatives
George Razvan Bacanu, Gabriela Hoffman, Michael Amponsah, Maria Concistrè, Richard J. Whitby, Malcolm H. Levitt
2020-05-13
Paper
DOI: 10.1039/D0CP01282C
DFT modelling of explicit solid–solid interfaces in batteries: methods and challenges
2020-02-11
Perspective
DOI: 10.1039/C9CP06485K
Structure and bonding of molecular stirrers with formula B7M2− and B8M2 (M = Zn, Cd, Hg)
Rui Yu, Jorge Barroso, Meng-hui Wang, Wei-yan Liang, Chen Chen, Ximena Zarate, Mesías Orozco-Ic, Gabriel Merino
2020-05-11
Paper
DOI: 10.1039/D0CP01603A
Polyamines stimulate RecA-mediated recombination by condensing duplex DNA and stabilizing intermediates
Naciye Esma Tirtom, Yang Hsu, Hung-Wen Li
2020-05-14
Paper
DOI: 10.1039/D0CP01061H
Sulfur hydrogen bonding and internal dynamics in the monohydrates of thenyl mercaptan and thenyl alcohol
Marcos Juanes, Rizalina Tama Saragi, Ruth Pinacho, José E. Rubio, Alberto Lesarri
2020-05-12
Paper
DOI: 10.1039/D0CP01706J
Direct imaging of direction-controlled molecular rotational wave packets created by a polarization-skewed double-pulse
Kenta Mizuse, Naoya Sakamoto, Romu Fujimoto, Yasuhiro Ohshima
2020-04-22
Paper
DOI: 10.1039/D0CP01084G
You might also like
Compound Q&A
What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?
4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...
333338-18-44-Nitrophenyl phosph...
Compound Q&A
What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?
2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...
1060816-01-42-(Trifluoromethyl)-...
Compound Q&A
How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?
2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...
137045-30-82-Fluoro-4-biphenylc...
Compound Q&A
What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?
Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...
61549-70-0Prednisolone-21-Carb...
Compound Q&A
How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?
4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...
3614-72-04-(Hydrazinomethyl)-...
Compound Q&A
What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?
4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...
92534-70-84-Amino-1-methyl-1H-...
Compound Q&A
What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?
Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...
77012-31-8Dehydropachymic acid
Compound Q&A
What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?
The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...
898561-66-56-[(2,2-Dimethylprop...
Compound Q&A
How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?
1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...
57709-62-31,10-Phenanthroline-...
Compound Q&A
How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?
5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...
113952-21-95-Carbamoyl-11-oxo-1...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.