Intramolecular difunctionalization of methylenecyclopropanes tethered with carboxylic acid by visible-light photoredox catalysis
Literature Information
Publication Date
2021-06-15
DOI
10.1039/D1QO00564B
Impact Factor
5.281
Authors
Hao-Zhao Wei, Yin Wei
View Original
Abstract
We have developed a visible-light photoredox catalyzed intramolecular difunctionalization of MCPs to access spiro[cyclopropane-1,2-indan]one from easily prepared methylenecyclopropanes tethered with carboxylic acid. The reaction can be performed under mild conditions, affording target products in excellent yields with a high atomic economy, and this cyclization reaction can be extended to gram scale synthesis. The products could be transformed to 1-indanone motifs existing in many natural products and bioactive compounds.
Related Literature
Local rotational symmetry in the packing of uniform spheres
Z. A. Tian, K. J. Dong, A. B. Yu
2017-05-10
Paper
DOI: 10.1039/C7CP01152K
Effects of orientation at the phthalocyanine–CdSe interface on the electron transfer characteristics
B. V. Nazarchuk, V. V. Golovanova, N. V. Tkachenko, T. T. Rantala
2017-03-24
Paper
DOI: 10.1039/C7CP00833C
New insights into the chemistry of ionic alkylorganic carbonates: a computational study
Khaleel I. Assaf, Abdussalam K. Qaroush, Ala'a F. Eftaiha
2017-05-17
Paper
DOI: 10.1039/C7CP02087B
Buckling behaviour of composites with double walled nanotubes from carbon and phosphorus
Jing Wan, Likui Yang, Ning Wei, Jiao Shi, Qing-Hua Qin
2017-03-28
Paper
DOI: 10.1039/C7CP01274H
Intracellular-molecular changes in plasma-irradiated budding yeast cells studied using multiplex coherent anti-Stokes Raman scattering microscopy
Ryo Furuta, Naoyuki Kurake, Kenji Ishikawa, Keigo Takeda, Hiroshi Hashizume, Hiroki Kondo, Takayuki Ohta, Masafumi Ito, Makoto Sekine, Masaru Hori
2017-04-27
Communication
DOI: 10.1039/C7CP00489C
GaS0.5Te0.5 monolayer as an efficient water splitting photocatalyst
Yujie Bai, Qinfang Zhang, Gaixia Luo, Yali Bu, Lei Zhu, Lele Fan, Baolin Wang
2017-05-22
Paper
DOI: 10.1039/C7CP01627A
Investigating the optical properties of BOIMPY dyes using ab initio tools
Boris Le Guennic, Giovanni Scalmani, Michael J. Frisch, Adèle D. Laurent
2017-03-28
Paper
DOI: 10.1039/C7CP01190C
Electronic characterization of Geobacter sulfurreducens pilins in self-assembled monolayers unmasks tunnelling and hopping conduction pathways
Krista M. Cosert, Rebecca J. Steidl, Angelines Castro-Forero, Robert M. Worden, Gemma Reguera
2017-03-30
Paper
DOI: 10.1039/C7CP00885F
Unexpected coordination number and phase diagram of niobium diselenide under compression
Zhong-Li Liu, Hong Jia, Rui Li, Xiu-Lu Zhang, Ling-Cang Cai
2017-05-03
Paper
DOI: 10.1039/C7CP00805H
You might also like
Compound Q&A
How should waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3) be handled?
Waste containing N-Methoxy-N-methyl-1,3-thiazole-5-carboxamide (CAS: 898825-89-3...
898825-89-3N-Methoxy-N-methyl-1...
Compound Q&A
How should N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine (CAS: 1318338-47-4) be stored?
N-(4-Biphenylyl)dibenzo[b,d]furan-4-amine should be stored in a tightly sealed c...
1318338-47-4N-(4-Biphenylyl)dibe...
Compound Q&A
What is the market or research trend for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1)?
The market for 3-Acetamido-5-amino-2,4,6-triiodobenzoic acid (CAS: 1713-07-1) is...
1713-07-13-Acetamido-5-amino-...
Compound Q&A
How should Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) be stored?
Benzyl 2-O-acetyl-3,4,6-tri-O-benzyl-beta-D-galactopyranoside (CAS: 61820-03-9) ...
61820-03-9Benzyl 2-O-acetyl-3,...
Compound Q&A
What regulatory guidelines apply to 2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3)?
2-Ethylpiperazine dihydrochloride (CAS: 438050-52-3) is regulated under the Glob...
438050-52-32-Ethylpiperazine di...
Compound Q&A
What regulatory guidelines apply to 1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 119462-56-5)?
1,1'-[1,3-Phenylenebis(methylene)]bis(3-methyl-1H-pyrrole-2,5-dione) (CAS: 11946...
119462-56-51,1'-[1,3-Phenyleneb...
Compound Q&A
Are there alternatives to 5-Fluoro-2-(1-pyrrolidinyl)pyridine (CAS: 1287217-79-1) in synthesis?
Several alternatives can be used in the synthesis of 5-Fluoro-2-(1-pyrrolidinyl)...
1287217-79-15-Fluoro-2-(1-pyrrol...
Compound Q&A
What precautions should be taken when handling 1-((2R,3R,4R,5R)-5-((bis(4-methoxyphenyl)(phenyl)methoxy)methyl)-4-hydroxy-3-methoxytetrahydrofuran-2-yl)-5-methylpyrimidine-2,4(1H,3H)-dione (CAS: 153631-19-7)?
Proper personal protective equipment (PPE) must be worn when handling this compo...
153631-19-71-((2R,3R,4R,5R)-5-(...
Compound Q&A
What precautions should be taken when handling 6-Bromoimidazo[1,2-a]pyridin-8-amine (CAS: 676371-00-9)?
When handling 6-Bromoimidazo[1,2-a]pyridin-8-amine, it is important to wear appr...
676371-00-96-Bromoimidazo[1,2-a...
Compound Q&A
Are there alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochloride (CAS: 1049740-22-8) in synthesis?
Alternatives to (2S,4R)-4-(4-Nitrobenzyl)pyrrolidine-2-carboxylic acid hydrochlo...
1049740-22-8(2S,4R)-4-(4-Nitrobe...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
3-(Methylamino)-1-phenyl-1-propanone hydrochloride (1:1)
CAS Number:
2538-50-3
Molecular Formula:
C10H14ClNO
![N-[(Benzyloxy)carbonyl]serine structure](https://static.chemtradehub.com/structs/276/2768-56-1-77f7.webp "N-[(Benzyloxy)carbonyl]serine structure")
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.