Blue light driven free-radical polymerization using arylazo sulfones as initiators
Literature Information
Andrea Nitti, Angelo Martinelli, Fabrice Batteux, Stefano Protti, Maurizio Fagnoni, Dario Pasini
The polymerization of a broad range of electron-poor olefins has been achieved under free-radical conditions by using arylazo sulfones as visible light photoinitiators. The process proceeds smoothly at room temperature both in bulk and in the presence of solvents upon irradiation with a 40 W Kessil lamp (456 nm, blue light) in the absence of any co-initiators or additives. High molecular weight polymers are obtained in excellent yields.
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