Surfactant-free emulsion polymerization of vinylidene fluoride mediated by RAFT/MADIX reactive poly(ethylene glycol) polymer chains
Literature Information
Publication Date
2021-09-13
DOI
10.1039/D1PY00728A
Impact Factor
5.582
Authors
Mathieu Fuentes-Exposito, Sébastien Norsic, Thibaut Février, Pierre-Yves Dugas, Salima Boutti, Samuel Devisme, Anthony Bonnet, Franck D'Agosto, Muriel Lansalot
View Original
Abstract
A robust and straightforward synthesis of surfactant-free poly(vinylidene fluoride) (PVDF) latexes is presented using RAFT/MADIX-mediated emulsion polymerization. VDF emulsion polymerizations were conducted in the presence of commercial poly(ethylene glycol) chains (PEG-OH) and in the presence of the same chains carrying a dithiocarbonate (xanthate) chain end (PEG-X). The identification of the stabilization mode in both cases is carefully examined, considering the irreversible chain transfer reactions well known in VDF free radical polymerization. The particle size is significantly smaller when PEG-X was used, demonstrating the positive effect on particle stabilization of the involvement of xanthate chain end in the free radical process.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
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Recommended Compounds
![(2S)-2-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-4-pentynoic acid structure](https://static.chemtradehub.com/structs/630/63039-48-5-b66d.webp "(2S)-2-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-4-pentynoic acid structure")
(2S)-2-({[(2-Methyl-2-propanyl)oxy]carbonyl}amino)-4-pentynoic acid
CAS Number:
63039-48-5
Molecular Formula:
C10H15NO4
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