Synthesis and anionic polymerization of isosorbide mono-epoxides for linear biobased polyethers
Literature Information
Publication Date
2021-10-12
DOI
10.1039/D1PY00687H
Impact Factor
5.582
Authors
Livia Matt, Ilme Liblikas, Olivier Bonjour, Lauri Vares
View Original
Abstract
A series of regioisomeric isosorbide mono-epoxides, as well as diastereomerically pure mono-epoxy derivatives, have been prepared and studied. Anionic ring-opening polymerization of methoxy-capped monomers produced linear polyethers tethered with isosorbide units. These reasonably high molecular weight polymers exhibited glass transition temperatures at around 10–15 °C and thermal stability up to ∼300 °C, which indicated that the mono-epoxides are promising building blocks for well-defined biobased polymers.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
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