A highly efficient metal-free protocol for the synthesis of linear polydicyclopentadiene

Literature Information

Publication Date 2021-04-14
DOI 10.1039/D1PY00191D
Impact Factor 5.582
Authors

Xuejin Yang, Laura M. Murphy, Scott M. Grayson


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Abstract

We have achieved breakthroughs for the efficient synthesis of linear polydicyclopentadiene (pDCPD) via photoredox mediated metal-free ring-opening metathesis polymerization (MF-ROMP). Molecular weight control from 1 to 16 kDa can be targeted in a straightforward manner. Assisted by this method, the Tg–Mn dependence of linear pDCPD is investigated and reported for the first time.

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Polymer Chemistry

Polymer Chemistry
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