Achieving enhanced solid-state photochromism and mechanochromism by introducing a rigid steric hindrance group

Literature Information

Publication Date 2021-07-22
DOI 10.1039/D1CP02983E
Impact Factor 3.676
Authors

Junzhao He, Huimin Zhao, Han Wu, Zhaohui Wang, Zhe He


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Abstract

For photochromic molecules, effective isomerization usually requires conformational freedom, which is usually unavailable under solvent-free conditions. In this work, we report a new method, which can realize the reversible switching of spiropyran molecules by introducing a rigid aromatic ring group and this method can provide the required free volume to transform from a closed-ring to an open-ring form. This new molecule can quickly change color in the solid state under ultraviolet light, and can be erased after being heated at 60 °C for about 5 minutes. Furthermore, this new compound presents mechanochromicity when a mechanical force is applied. What is more, it can be used for at least 30 cycles of print–erase operations without apparent fatigue. This new molecule exhibits improved photochromic and anti-fatigue properties in the solid state, which can promote its application in both ultraviolet printing and anti-counterfeiting materials.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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