Photochemical synthesis of 3-hydroxyphenanthro[9,10-c]furan-1(3H)-ones from α-keto acids and alkynes
Literature Information
Publication Date
2021-01-04
DOI
10.1039/D0QO01487G
Impact Factor
5.281
Authors
Beibei Zhao, Zhen Zhang, Yu Ge, Pinhua Li, Tao Miao
View Original
Abstract
A novel and efficient method for the synthesis of 3-hydroxyphenanthro[9,10-c]furan-1(3H)-ones has been achieved from readily available α-keto acids and alkynes through photo-initiated transformation, providing a range of structurally diverse products in good to excellent yields under mild conditions. Mechanistic studies reveal that this reaction undergoes photo-induced radical addition/cyclization and hydrogen evolution cascade processes.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
![Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure](https://static.chemtradehub.com/structs/121/12150-46-8-ecd2.webp "Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron structure")
Bis[(1,2,3,4,5-eta)-1-(diphenylphosphino)cyclopentadienyl]iron
CAS Number:
12150-46-8
Molecular Formula:
C34H28FeP2
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