Kinetic analysis of the ozone processing of an unsaturated organic monolayer as a model of an aerosol surface
Literature Information
Erick González-Labrada, Rolf Schmidt, Christine E. DeWolf
It has been suggested that an organic aerosol containing unsaturated organic compounds at the surface would likely be processed by atmospheric ozone. The ozonolysis of oleic acid gives rise to the formation of products having shorter chain lengths than the starting molecule, and are consequently more water soluble than oleic acid. Hence, the exposure of a monolayer of oleic acid to ozone should lead to a decrease in surface activity at the air–water interface. A model system is used for real-time measurements of surface tension changes due to ozone exposure of a pendant drop that is coated by a fatty acid monolayer. The surface tension is measured based on an analysis of the shape profile of acquired images of the drop. A study of the kinetics of the gas-surface reaction is presented. Assuming that the uptake of ozone is dominated by the reaction at the surface, the measured reactive uptake coefficient of ozone γmeas is estimated to be (2.6 ± 0.1) × 10−6.
Related Literature
Molecular dynamics study of dicarbollide anions in nitrobenzene solution and at its aqueous interface. Synergistic effect in the Eu(iii) assisted extraction
G. Chevrot, R. Schurhammer, G. Wipff
DOI: 10.1039/B711284J
On the photochemistry of IONO2 : absorption cross section (240–370 nm) and photolysis product yields at 248 nm
D. M. Joseph, S. H. Ashworth, J. M. C. Plane
DOI: 10.1039/B709465E
Low-volatility poly-oxygenates in the OH-initiated atmospheric oxidation of α-pinene: impact of non-traditional peroxyl radical chemistry
L. Vereecken, J.-F. Müller, J. Peeters
DOI: 10.1039/B708023A
Theory and computation of nuclear magnetic resonance parameters
Juha Vaara
DOI: 10.1039/B706135H
Small angle X-ray scattering measurements probe water nanodroplet evolution under highly non-equilibrium conditions
Barbara E. Wyslouzil, Gerald Wilemski, Reinhard Strey, Soenke Seifert, Randall E. Winans
DOI: 10.1039/B709363B
Oxygen-17 hyperfine structures in the pure rotational spectra of SrO, SnO, BaO, HfO and ThO
Christopher T. Dewberry, Kerry C. Etchison, Garry S. Grubbs II, Robert A. Powoski, Michal M. Serafin, Sean A. Peebles, Stephen A. Cooke
DOI: 10.1039/B712798G
Potential energy surface for cyclotrimethylene trinitramine dimer from symmetry-adapted perturbation theory‡
Robert Bukowski, Betsy M. Rice
DOI: 10.1039/B709192C
You might also like
What is Ethyl 3-cyclohexylpropanoate (CAS: 10094-36-7)?
Ethyl 3-cyclohexylpropanoate is a clear, colorless to light yellow liquid with a...
How should waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl)nicotinic acid (CAS: 34783-31-8) be handled?
Waste containing 2-(Hydroxymethyl)-5-(methoxycarbonyl)-6-methyl-4-(2-nitrophenyl...
How should waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) be handled?
Waste containing 2,4,6-Tris(pentafluoroethyl)-1,3,5-triazine (CAS: 858-46-8) sho...
What precautions should be taken when handling Chloroac-nle-oh (CAS: 56787-36-1)?
When handling Chloroac-nle-oh (CAS: 56787-36-1), it is essential to wear appropr...
What industries use Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 752244-05-6)?
Ethyl 6-phenylimidazo[2,1-b][1,3]thiazole-3-carboxylate is primarily used in the...
Are there alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis?
Alternatives to alpha-(2-Bromophenyl)benzylamine (CAS: 55095-15-3) in synthesis ...
How should waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) be handled?
Waste containing 2-Chloro-5-methoxypyridine (CAS: 139585-48-1) should be managed...
What industries use 1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9)?
1-(4-Methoxyphenyl)-2,5-dimethyl-1H-pyrrole (CAS: 5044-27-9) is used in various ...
Are there alternatives to 3-Bromo-5-(N-Boc)aminomethylisoxazole (CAS: 903131-45-3) in synthesis?
There are alternative reagents and compounds that can be used in the synthesis o...
What is Tungsten(IV) oxide (CAS: 12036-22-5)?
Tungsten(IV) oxide, also known as tungsten dioxide, is a chemical compound with ...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.











![1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure 1-(Hexopyranosyloxy)-4a,5-dihydroxy-7-methyl-1,4a,5,6,7,7a-hexahydrocyclopenta[c]pyran-7-yl 3-phenylacrylate structure](https://static.chemtradehub.com/structs/192/19210-12-9-ecae.webp)


