Recent progress in the usage of tetrabromo-substituted naphthalenetetracarboxylic dianhydride as a building block to construct organic semiconductors and their applications
Literature Information
Zongrui Wang, Hua Li, Jianmei Lu
Tetrabromo-substituted naphthalenetetracarboxylic dianhydrides (TBNDA) have attracted considerable attention in constructing organic semiconductors (OSCs) for diverse applications in the past decade. A series of synthetic strategies have been developed to modify the parent structure, including longitudinal imidization and lateral core-functionalization. The as-obtained small molecular and polymeric materials present expanded conjugated systems with unique characteristics of near-infrared absorption, outstanding π-acidity, and low-lying LUMO levels. In this review, recent progress in the synthetic methods of the TBNDI derivatives and their applications in organic field-effect transistors (OFETs), gas sensors, fluoride sensors, and supramolecular self-assembly are summarized. The remaining opportunities and challenges are elaborated to give specific guidance on preparing abundant TBNDA derivatives and their anticipated applications.
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Organic Chemistry Frontiers

Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry










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