tert-Butyl 4-chloro-5-methoxypyridin-3-ylcarbamate
CAS Number:
1045858-17-0
Molecular Formula:
C11H15ClN2O3
Polyester nitrile N-oxides for click reactions synthesized with nitroalkane precursors as the initiator
Literature Information
Publication Date
2020-03-27
DOI
10.1039/D0PY00278J
Impact Factor
5.582
Authors
Toyokazu Tsutsuba, Hiromitsu Sogawa
View Original
Abstract
Polyesters that have a nitrile N-oxide function at the initiation end were prepared and applied to a catalyst-free click reaction for star polymer synthesis. They were obtained by an initial living ring-opening polymerization of lactide and lactones with an alcohol-bearing nitroalkane as the initiator, followed by conversion of the nitroalkane to a nitrile N-oxide function. The resulting polymer and block copolymer nitrile N-oxides showed very high reactivity toward a hexakis(alkenyl) core to give the corresponding star polymers via complete conversion.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
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