Potential of N2/O2 atmospheric pressure needle-water DC microplasmas for nitrogen fixation: nitrite-free synthesis of nitrates

Literature Information

Publication Date 2020-10-16
DOI 10.1039/D0CP03858J
Impact Factor 3.676
Authors

C. Pattyn, N. Maira, A. Remy, N. C. Roy, S. Iseni, D. Petitjean, F. Reniers


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Abstract

A needle-water DC microplasma system working at atmospheric pressure in N2/O2 gas mixtures is used to study the fundamental mechanisms of nitrate/nitrite synthesis in highly complex and yet little-known plasma–water systems. Plasma properties are investigated by means of optical emission spectroscopy while the activated water is analyzed following the treatment using ionic chromatography and UV-Vis absorbance spectroscopy. Experiments highlight that the energy efficiency and selectivity of the process are influenced by the oxygen content and the plasma-induced water heating, with strong differences when the water surface is the anode or the cathode electrode. Nitrates are successfully synthesized without residual nitrites in the solution with a comparatively higher energy efficiency when the water is the cathode. The possible reactions involved in the gas phase and aqueous phase chemistry are presented and future scope for the optimization of the system is discussed.

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Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
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Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

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