C–C coupling reactions promoted by CNT-supported bimetallic center in Fischer–Tropsch synthesis
Literature Information
Publication Date
2020-02-18
DOI
10.1039/C9SE01289C
Impact Factor
6.367
Authors
Chi-You Liu, Elise Y. Li
View Original
Abstract
C–C coupling efficiency is the most important aspect in Fischer–Tropsch synthesis (FTS). Different promoters and supports are reported to increase the selectivity of desired products in FTS. This work considers three critical C–C coupling reactions catalyzed by bimetallic systems based on N-doped CNTs. We report the theoretical reaction barriers for these reactions that are affected by the extents of electron transfer as well as the electronic structure of the adsorbates in different reaction mechanisms. We propose a novel Co/Mn bimetallic center supported on the N-doped CNT surface that could convert CO more efficiently to long chain carbon products with a low C–C coupling reaction barrier, leading to a suppressed C1 selectivity in FTS.
Recommended Journals
Related Literature
Hierarchical ordering and multilayer structure of poly(ε-caprolactone) end-functionalized by a liquid crystalline unit: role of polymer crystallization
Wenqing Xu, Xing Li, Wenhua Yuan, Jian Zhou
2021-07-05
Paper
DOI: 10.1039/D1PY00702E
A pillar[5]arene-based 3D polymer network for efficient iodine capture in aqueous solution
Jiajun Cao, Huangtianzhi Zhu, Liqing Shangguan, Yuezhou Liu, Peiren Liu, Qi Li, Yitao Wu
2021-05-27
Communication
DOI: 10.1039/D1PY00535A
Cross-linked polyurethane with dynamic phenol-carbamate bonds: properties affected by the chemical structure of isocyanate
Jiaxin Shi, Tianze Zheng, Yao Zhang, Baohua Guo, Jun Xu
2021-03-23
Paper
DOI: 10.1039/D1PY00157D
Efficient synthesis of discrete oligo(fluorenediacetylene)s toward chain-length-dependent optical and structural properties
Xianheng Shi, Min Liu, Lishan Li, Jiandong Zhang, Haiyan Li, Zhihao Huang, Wei Zhang, Zhengbiao Zhang, Nianchen Zhou, Xiulin Zhu
2021-03-31
Paper
DOI: 10.1039/D1PY00165E
Poly[glycidyl oligo(oxyethylene)carbamate]s (PGn-EOmR′ and R-PGn-EOmR′): controlled synthesis and effects of molecular parameters (n and m), side groups (R′), and end-groups (R) on thermoresponsive properties
Tingyu He, Yanqiu Wang, Liang Xu, Xiangming Fu, Atsushi Narumi, Shin-ichiro Sato
2021-03-31
Paper
DOI: 10.1039/D1PY00070E
Toughened PLA-b-PCL-b-PLA triblock copolymer based biomaterials: effect of self-assembled nanostructure and stereocomplexation on the mechanical properties
Neha Mulchandani, Kazunari Masutani, Sachin Kumar, Hideki Yamane, Yoshiharu Kimura, Vimal Katiyar
2021-06-18
Paper
DOI: 10.1039/D1PY00429H
NMR investigations of polytrifluoroethylene (PTrFE) synthesized by RAFT
Vincent Bouad, Marc Guerre, Sami Zeliouche, Bruno Améduri, Cédric Totée, Gilles Silly, Rinaldo Poli, Vincent Ladmiral
2021-03-15
Paper
DOI: 10.1039/D0PY01753A
Polymer defect engineering – conductive 2D organic platelets from precise thiophene-doped polyethylene
Oksana Suraeva, Beomjin Jeong, Kamal Asadi, Katharina Landfester, Ingo Lieberwirth
2021-03-02
Paper
DOI: 10.1039/D1PY00117E
Heterotellurium-containing macrocycles towards degradable tellurium-functionalized polymers
Jieni Hu, Chuanhao Sun, Siqi Li, Yuan Yuan
2021-07-20
Communication
DOI: 10.1039/D1PY00703C
You might also like
Compound Q&A
What industries use (1R,3S)-1,3-Cyclopentanediol (CAS: 16326-97-9)?
(1R,3S)-1,3-Cyclopentanediol finds applications in various industries. In the ph...
16326-97-9(1R,3S)-1,3-Cyclopen...
Compound Q&A
What precautions should be taken when handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine (CAS: 637-31-0)?
When handling N'-[4-(Dimethylamino)phenyl]-N,N-dimethyl-1,4-benzenediamine, it i...
637-31-0N'-[4-(Dimethylamino...
Compound Q&A
Are there alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine (CAS: 1352318-16-1) in synthesis?
There are several alternatives to 5-(2,4-Difluorophenyl)-2-methoxypyrimidine in ...
1352318-16-15-(2,4-Difluoropheny...
Compound Q&A
What regulatory guidelines apply to 1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6)?
1-(3-Methoxyphenoxy)propan-2-ol (CAS: 382141-68-6) must comply with the Globally...
382141-68-61-(3-Methoxyphenoxy)...
Compound Q&A
Is Tetrodotoxin Citrate (CAS: 18660-81-6) safe?
Tetrodotoxin Citrate is extremely dangerous and should be handled with extreme c...
18660-81-6Tetrodotoxin Citrate
Compound Q&A
What are the main uses of 2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9)?
2-Methyl-2-propanyl [(1R,3S)-3-hydroxycyclopentyl]carbamate (CAS: 225641-84-9) i...
225641-84-92-Methyl-2-propanyl ...
Compound Q&A
How should waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) be handled?
Waste containing 4-(2-Hydroxyhexafluoroisopropyl)Benzoic Acid (CAS: 16261-80-6) ...
16261-80-64-(2-Hydroxyhexafluo...
Compound Q&A
How is 2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl}carbamate (CAS: 102507-19-7) typically synthesized?
2-Methyl-2-proanyl {(2S)-1-[(benzyloxy)amino]-3-hydroxy-3-methyl-1-oxo-2-butanyl...
102507-19-72-Methyl-2-propanyl ...
Compound Q&A
What is Benzeneethanamine, α-ethyl-, hydrochloride (1:1) (CAS: 20735-15-3)?
Benzeneethanamine, α-ethyl-, hydrochloride (1:1) is an organic compound with the...
20735-15-3Benzeneethanamine, α...
Compound Q&A
Are there alternatives to 3-{(E)-[4-(Dimethylamino)phenyl]diazenyl}benzoic acid (CAS: 20691-84-3) in synthesis?
In the synthesis of compounds similar to 3-{(E)-[4-(Dimethylamino)phenyl]diazeny...
20691-84-33-{(E)-[4-(Dimethyla...
Source Journal
Recommended Compounds
(2R,4R)-1-Boc-4-Aminopyrrolidine-2-carboxylic acid
CAS Number:
132622-98-1
Molecular Formula:
C10H18N2O4
5-Phenyl-1-(pyridin-3-ylsulfonyl)-1H-pyrrole-3-carbaldehyde
CAS Number:
881676-90-0
Molecular Formula:
C16H12N2O3S
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.