![tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure](https://static.chemtradehub.com/structs/336/336191-16-3-bb55.webp "tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate structure")
tert-butyl 8-benzyl-2,8-diazaspiro[4.5]decane-2-carboxylate
CAS Number:
336191-16-3
Molecular Formula:
C20H30N2O2
A pillar[5]arene-based 3D polymer network for efficient iodine capture in aqueous solution
Literature Information
Publication Date
2021-05-27
DOI
10.1039/D1PY00535A
Impact Factor
5.582
Authors
Jiajun Cao, Huangtianzhi Zhu, Liqing Shangguan, Yuezhou Liu, Peiren Liu, Qi Li, Yitao Wu
View Original
Abstract
Iodine in wastewater can cause environmental pollution that encourages the development of materials for iodine removal. Herein, a novel pillar[5]arene-based 3D polymer network, which is easily constructed via a crosslinking reaction between a pillar[5]arene and DL-dithiothreitol, is applied for efficient iodine removal. Benefitting from fast and simple preparation, this polymer can be obtained on a large scale. UV-vis and Raman analyses demonstrate that the 3D polymer network can efficiently adsorb iodine from water because of diol units and the hydrophobic nature of the pillararene. The structure of the polymer after iodine capture is found to be unchanged, indicating that iodine capture is driven by non-covalent interactions mainly including hydrogen bonding and hydrophobic interactions. Besides, this polymer is recyclable and can be reused five times with little loss of performance.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
5-(2-Methyl-3-furyl)-4-phenyl-2,4-dihydro-3H-1,2,4-triazole-3-thione
CAS Number:
346464-59-3
Molecular Formula:
C13H11N3OS
![6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure](https://static.chemtradehub.com/structs/926/926319-53-1-2287.webp "6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one structure")
6-(Benzyloxy)-8-(2-bromoacetyl)-2H-benzo[b][1,4]oxazin-3(4H)-one
CAS Number:
926319-53-1
Molecular Formula:
C17H14BrNO4
4-(Bromomethyl)-1-cyclohexyl-2-(trifluoromethyl)benzene
CAS Number:
800381-60-6
Molecular Formula:
C14H16BrF3
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