Cascade cyclization reactions of alkylidenecyclopropanes for the construction of polycyclic lactams and lactones by visible light photoredox catalysis
Literature Information
Publication Date
2019-12-10
DOI
10.1039/C9QO01360A
Impact Factor
5.281
Authors
Mintao Chen, Yin Wei
View Original
Abstract
A visible light photocatalytic cascade cyclization reaction of alkylidenecyclopropanes for the rapid construction of seven- and eight-membered ring-containing polycyclic lactams and lactones has been developed. The process is proposed to proceed through a radical pathway, and the suggested radical intermediate was captured by TEMPO successfully. An intermolecular version of the reaction was also achieved, affording a variety of methyl dialinoacetate products.
Related Literature
Dissociative recombination of N2OD+
W. D. Geppert, R. Thomas, F. Hellberg, A. Ehlerding, F. Österdahl, M. af Ugglas, M. Larsson
2004-05-10
Paper
DOI: 10.1039/B403461A
Quantifying hydrogen-bonding strength: the measurement of 2hJNN couplings in self-assembled guanosines by solid-state 15N spin-echo MAS NMR
John M. Griffin, Stefano Masiero, Stefano Lena, Giovanni Gottarelli, Paul Hodgkinson, Claudiu Filip, Steven P. Brown
2007-04-25
Paper
DOI: 10.1039/B703513F
Impurity enhancement effects in the frame of the five-frequency model
István A. Szabó, Dezső L. Beke
2004-06-10
Paper
DOI: 10.1039/B316764J
A critical assessment on two predictive models of binary vapor–liquid equilibrium
Hansong Cheng, Virpul Parekh, Brian Peterson, Kamil Klier
2004-06-10
Paper
DOI: 10.1039/B400322E
Ab initio study of chiral recognition in the propylene imine·hydrogen peroxide complex
Zheng Su, Yunjie Xu
2005-05-26
Paper
DOI: 10.1039/B504191K
The nature of the oxidation states of gold on ZnO
N. S. Phala, G. Klatt, E. van Steen, S. A. French, A. A. Sokol
2005-05-16
Paper
DOI: 10.1039/B501266J
Probing factors affecting the gas phase stabilities of noncovalent complexes formed by peptides bound to the Grb2 SH2 domain protein
M. Isabel Catalina, Nico J. de Mol, Marcel J. E. Fischer, Albert J. R. Heck
2004-02-23
Paper
DOI: 10.1039/B315435A
Comparison of the modified Poisson–Boltzmann theory with recent density functional theory and simulation results in the planar electric double layer
Christopher W. Outhwaite
2004-04-26
Paper
DOI: 10.1039/B316098J
A theoretical study of water clusters: the relation between hydrogen-bond topology and interaction energy from quantum-chemical computations for clusters with up to 22 molecules
Annika Lenz, Lars Ojamäe
2005-04-12
Paper
DOI: 10.1039/B502109J
You might also like
Compound Q&A
How should waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane be handled?
Waste containing (6-Bromo-2-naphthyl)oxy](dimethyl)(2-methyl-2-propanyl)silane (...
100751-65-3[(6-Bromo-2-naphthyl...
Compound Q&A
How is 7-Fluoro-4-isoquinolinecarboxylic acid (CAS: 1841081-40-0) typically synthesized?
7-Fluoro-4-isoquinolinecarboxylic acid can be synthesized via a multi-step proce...
1841081-40-07-Fluoro-4-isoquinol...
Compound Q&A
What are the physical and chemical properties of 2,3,5,6-Tetrabromothieno[3,2-b]thiophene (CAS: 124638-53-5)?
2,3,5,6-Tetrabromothieno[3,2-b]thiophene is a crystalline compound with a high m...
124638-53-52,3,5,6-Tetrabromoth...
Compound Q&A
Is 1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indole-4-carboxamide (CAS: 1542705-92-9) safe?
1-[4-(Benzylamino)-7,8-dihydro-5H-pyrano[4,3-d]pyrimidin-2-yl]-2-methyl-1H-indol...
1542705-92-91-[4-(Benzylamino)-7...
Compound Q&A
What is the market or research trend for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3-methyl-4-oxo- (CAS: 113942-30-6)?
The market for imidazo[5,1-d]-1,2,3,5-tetrazine-8-carboxylic acid, 3,4-dihydro-3...
113942-30-6Imidazo[5,1-d]-1,2,3...
Compound Q&A
What is 3-(Triisopropylsilyl)propiolaldehyde (CAS: 163271-80-5)?
3-(Triisopropylsilyl)propiolaldehyde is a synthetic organic compound with the CA...
163271-80-53-(Triisopropylsilyl...
Compound Q&A
What regulatory guidelines apply to 6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1)?
6-Nitro-2H-1,4-benzoxazin-3(4H)-one (CAS: 81721-87-1) is subject to various regu...
81721-87-16-Nitro-2H-1,4-benzo...
Compound Q&A
How should waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piperazinyl)acetic acid (CAS: 885272-91-3) be handled?
Waste containing (3-Fluorophenyl)(4-{[(2-methyl-2-propanyl)oxy]carbonyl}-1-piper...
885272-91-3(3-Fluorophenyl)(4-{...
Compound Q&A
What are the physical and chemical properties of N,N'-4,4'-Biphenyldiyldiisonicotinamide (CAS: 55119-40-9)?
N,N'-4,4'-Biphenyldiyldiisonicotinamide is a white crystalline solid with a mole...
55119-40-9N,N'-4,4'-Biphenyldi...
Compound Q&A
What industries use 6-Bromo-8-fluoro-2-quinazolinol (CAS: 1036756-15-6)?
6-Bromo-8-fluoro-2-quinazolinol is primarily used in the pharmaceutical industry...
1036756-15-66-Bromo-8-fluoro-2-q...
Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
Recommended Compounds
Recommended Suppliers
Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.