Transition-metal-free borylation of propargylic alcohols: structurally variable synthesis in ionic liquid medium
Literature Information
Publication Date
2019-04-16
DOI
10.1039/C9QO00322C
Impact Factor
5.281
Authors
Sangepu Bhavanarushi, Yin Xu, Imran Khan, Zhibin Luo, Bin Liu, Jimin Xie
View Original
Abstract
Terminal or electron-deficient alkynes had been widely applied in transition-metal-free (TM-free) borylation with diboron reagents, allowing the construction of various vinylboronate reagents. By contrast, borylative addition to electronic unbiased triple bonds remained challenging in the TM-free approach. To address this issue, we developed base-promoted borylation of internal propargylic alcohols in ionic liquid medium affording structurally variable vinylboronates.
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Source Journal
Organic Chemistry Frontiers
CiteScore:
7.8
Self-citation Rate:
8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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581802-26-8
Molecular Formula:
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Molecular Formula:
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