1-(3-Bromo-4-fluorophenyl)methanamine hydrochloride (1:1)
CAS Number:
202865-68-7
Molecular Formula:
C7H8BrClFN
Photocatalytic borylcyclopropanation of α-boryl styrenes
Literature Information
Publication Date
2019-03-20
DOI
10.1039/C9QO00197B
Impact Factor
5.281
Authors
Tsuyoshi Ohtani, Yuto Tsuchiya, Daisuke Uraguchi
View Original
Abstract
A diastereoselective borylcyclopropanation of α-MIDA-boryl styrenes with 1,1-diiodoborylmethane is developed using 1,2,3,5-tetrakis(carbazol-9-yl)-4,6-dicyanobenzene (4CzIPN) as a catalyst under visible-light irradiation. The scope of this photocatalytic method is explored, and the utility of the resulting doubly borylated cyclopropanes is demonstrated by the selective transformation of one of the two boryl groups.
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Source Journal
Organic Chemistry Frontiers
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7.8
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8.7%
Articles per Year:
724
Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry
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