Synthesis of a [20]phenacene dodeca-ester by controlled condensation of seven naphthalene-based building blocks

Literature Information

Publication Date 2019-02-20
DOI 10.1039/C9QO00125E
Impact Factor 5.281
Authors

Guillaume Naulet, Stéphanie Huet-Exiga, Harald Bock, Fabien Durola


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Abstract

Complementary protecting techniques for the Perkin reaction between arylacetic acids and arylglyoxylic acids efficiently allowed the multistep condensation of seven naphthalene fragments, linked by maleate bridges. Photocyclisation of this heptameric flexible precursor has led to a [20]phenacene dodeca-ester, the longest known phenacene to date.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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