![1-{2-[(4-Chlorobenzyl)sulfanyl]-2-(2,4-dichlorophenyl)ethyl}-1H-imidazole structure](https://static.chemtradehub.com/structs/613/61318-90-9-6785.webp "1-{2-[(4-Chlorobenzyl)sulfanyl]-2-(2,4-dichlorophenyl)ethyl}-1H-imidazole structure")
1-{2-[(4-Chlorobenzyl)sulfanyl]-2-(2,4-dichlorophenyl)ethyl}-1H-imidazole
CAS Number:
61318-90-9
Molecular Formula:
C18H15Cl3N2S
Star polymerization of norbornene derivatives using a tri-functionalized Blechert's olefin metathesis catalyst
Literature Information
Publication Date
2020-01-20
DOI
10.1039/C9PY01905G
Impact Factor
5.582
Authors
View Original
Abstract
Blechert's catalyst (III), one of the powerful olefin metathesis catalysts in ring closing metathesis (RCM), was demonstrated to show living ROMP characteristics towards conventional norbornene derivatives. The obtained homopolymers and block copolymers have very narrow Đ and controlled molecular weights. The tri-functionalized ROMP initiator (IV) based on Blechert's catalyst was isolated in good yield, and showed highly efficient activity in the star polymerization of norbornene derivatives, including bulky fourth generation dendrons, to afford tri-arm star polymers with a precise molecular weight and narrow Đ. The difference in the solution properties between tri-arm star polymers and linear polymers with similar molecular weights was studied by tandem GPC/light scattering.
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Source Journal
Polymer Chemistry
CiteScore:
8.6
Self-citation Rate:
7.3%
Articles per Year:
457
Polymer Chemistry welcomes submissions in all areas of polymer science that have a strong focus on macromolecular chemistry. Manuscripts may cover a broad range of fields, yet no direct application focus is required.
Recommended Compounds
![2-Methyl-2-propanyl 3-[2-(2-{[(4-methylphenyl)sulfonyl]oxy}ethoxy)ethoxy]propanoate structure](https://static.chemtradehub.com/structs/850/850090-13-0-26a7.webp "2-Methyl-2-propanyl 3-[2-(2-{[(4-methylphenyl)sulfonyl]oxy}ethoxy)ethoxy]propanoate structure")
2-Methyl-2-propanyl 3-[2-(2-{[(4-methylphenyl)sulfonyl]oxy}ethoxy)ethoxy]propanoate
CAS Number:
850090-13-0
Molecular Formula:
C18H28O7S
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