The disruption of verM activates the production of gliocladiosin A and B in Clonostachys rogersoniana
Literature Information
Publication Date
2019-06-28
DOI
10.1039/C9OB01102A
Impact Factor
3.876
Authors
Yuanyuan Pan, Xingzhong Liu, Yongsheng Che
View Original
Abstract
Gliocladiosin A (1) and B (2), two dipeptides conjugated with macrolides, were identified from a verM disruption mutant of the Cordycep-colonizing fungus Clonostachys rogersoniana. The structures and absolute configurations of 1 and 2 were determined on the basis of spectroscopic data analysis, including MS, NMR, CD and X-ray diffraction. A biogenetic pathway for 1 and 2 was proposed. These two compounds showed moderate antibacterial effects.
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Organic & Biomolecular Chemistry
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