Synchrotron-based Mössbauer spectroscopy characterization of sublimated spin crossover molecules

Literature Information

Publication Date 2020-02-26
DOI 10.1039/C9CP04464G
Impact Factor 3.676
Authors

Alberto Cini, Lorenzo Poggini, Alexander I. Chumakov, Rudolf Rüffer, Gabriele Spina, Alain Wattiaux, Mathieu Duttine, Mathieu Gonidec, Maria Fittipaldi, Patrick Rosa, Matteo Mannini


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Abstract

The spin crossover (SCO) efficiency of [57Fe(bpz)2(phen)] (where bpz = bis(pyrazol-1-yl)borohydride and phen = 9,10-phenantroline) molecules deposited on gold substrates was investigated by means of synchrotron Mössbauer spectroscopy. The spin transition was driven thermally, or light induced via the LIESST (light induced excited spin-state trapping) effect. Both sets of measurements show that, once deposited on a gold substrate, the efficiency of the SCO mechanism is modified with respect to molecules in the bulk phase. A correlation in the distribution of hyperfine parameters in the sublimated films, not evidenced so far in the bulk phase, is reported. This translates into geometrical distortions of the first coordination sphere of the iron atom that seem to correlate with the decreased spin conversion. The work reported clearly shows the potentiality of synchrotron Mössbauer spectroscopy for the characterization of nanostructured Fe-based SCO systems, thus resulting as a key tool in view of their applications in innovative nanoscale devices.

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Physical Chemistry Chemical Physics
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