Catalytic membrane-installed microchannel reactors for one-second allylic arylation

Literature Information

Publication Date 2009-08-18
DOI 10.1039/B912696A
Impact Factor 6.222
Authors

Yoichi M. A. Yamada, Kaoru Torii


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Abstract

A variety of catalytic membranes of palladium-complexes with linear polymer ligands were prepared inside a microchannel reactor via coordinative and ionic molecular convolution to provide catalytic membrane-installed microdevices, which were applied to the instantaneous allylic arylation reaction of allylic esters and aryl boron reagents under microflow conditions to afford the corresponding coupling products within 1 second of residence time.

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