Molecular QCA embedding in microporous materials

Literature Information

Publication Date 2019-03-25
DOI 10.1039/C9CP00832B
Impact Factor 3.676
Authors

Alberto M. Pintus, Andrea Gabrieli, Federico G. Pazzona, Giovanni Pireddu, Pierfranco Demontis


View Original

Abstract

We propose an environment for information encoding and transmission via a nanoconfined molecular Quantum Dot Cellular Automata (QCA) wire, composed of a single row of head-to-tail interacting 2-dots molecular switches. While most of the research in the field refers to dots-bearing molecules bound on some type of surface, forming a bidimensional array of square cells capable of performing QCA typical functions, we propose here to embed the information bearing elements within the channels of a microporous matrix. In this way molecules would self-assemble in a row as a consequence of adsorption inside the pores of the material, forming an encased wire, with the crystalline environment giving stability and protection to the structure. DFT calculations on a diferrocenyl carborane, previously proposed and synthesized [J. A. Christie, R. P. Forrest, S. A. Corcelli, N. A. Wasio, R. C. Quardokus, R. Brown, S. A. Kandel, Y. Lu, C. S. Lent and K. W. Henderson, Angew. Chem., Int. Ed., 2015, 54, 15448], were performed both in vacuum and inside the channels of zeolite ITQ-51, indicating that information encoding and transmission is possible within the nanoconfined environment.

Related Literature

Salt-induced reentrant hydrogel of poly(ethylene glycol)–poly(lactide-co-glycolide) block copolymers

Ting Li, Tianyuan Ci, Liang Chen, Lin Yu, Jiandong Ding

2013-09-26 Paper

DOI: 10.1039/C3PY01107K

Polymer-modified gold nanoparticles via RAFT polymerization: a detailed study for a biosensing application

Masaki Takara, Masayuki Toyoshima, Hirokazu Seto, Yu Hoshino, Yoshiko Miura

2013-09-20 Paper

DOI: 10.1039/C3PY01001E

Synthesis and volume phase transition of concanavalin A-based glucose-responsive nanogels

Ting Ye, Suting Yan, Yumei Hu, Li Ding, Weitai Wu

2013-08-07 Paper

DOI: 10.1039/C3PY00778B

(Meth)acrylic monomers with heteroatom-containing ester side chains: a systematic PLP-SEC and polymerization study

Marek Stach, Anna Chovancová, Andrea M. Misske, Igor Lacík

2013-09-03 Paper

DOI: 10.1039/C3PY00948C

Direct synthesis of poly(p-phenyleneethynylene)s from calcium carbide

Nopparat Thavornsin, Mongkol Sukwattanasinitt, Sumrit Wacharasindhu

2013-08-12 Communication

DOI: 10.1039/C3PY01068F

Synthesis and photovoltaic properties of a low bandgap BODIPY–Pt conjugated polymer

Wenhan He, Yingbing Jiang, Yang Qin

2013-10-22 Paper

DOI: 10.1039/C3PY01396K

Nonvolatile organic field-effect transistor memory devices using polymer electrets with different thiophene chain lengths

Ying-Hsuan Chou, Sanae Takasugi, Raita Goseki, Takashi Ishizone, Wen-Chang Chen

2013-10-14 Paper

DOI: 10.1039/C3PY01124K

You might also like

Compound Q&A

What are the main uses of 1H-Indazole-6-carbonitrile (CAS: 141290-59-7)?

1H-Indazole-6-carbonitrile finds applications in pharmaceuticals, where it serve...

141290-59-71H-Indazole-6-carbon...
Compound Q&A

How should waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) be handled?

Waste containing Dioctyl (2E)-2-butenedioate (CAS: 2997-85-5) should be collecte...

2997-85-5Dioctyl (2E)-2-buten...
Compound Q&A

What industries use Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide (CAS: 68291-98-5)?

Sodium [(1,2-benzoxazol-3-ylmethyl)sulfonyl]azanide is primarily used in pharmac...

68291-98-5Sodium [(1,2-benzoxa...
Compound Q&A

Are there alternatives to Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxylate (CAS: 741709-66-0) in synthesis?

Dimethyl 4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-2,6-pyridinedicarboxyla...

741709-66-0Dimethyl 4-(4,4,5,5-...
Compound Q&A

How should waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) be handled?

Waste containing 2-Fluoro-6-hydrazinopyridine (CAS: 80714-39-2) should be manage...

80714-39-22-Fluoro-6-hydrazino...
Compound Q&A

What is 6-Formyl-2-pyridinecarboxylic acid (CAS: 499214-11-8)?

6-Formyl-2-pyridinecarboxylic acid is an organic compound with the molecular for...

499214-11-86-Formyl-2-pyridinec...
900874-91-13-(3,4-dimethoxyphen...
Compound Q&A

How is 9H-Tribenzo[b,d,f]azepine (CAS: 29875-73-8) typically synthesized?

9H-Tribenzo[b,d,f]azepine is typically synthesized via a multi-step process invo...

29875-73-89H-Tribenzo[b,d,f]az...
Compound Q&A

How is 1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxylic acid (CAS: 1797982-51-4) typically synthesized?

1-Cyclopropyl-7-ethoxy-6-fluoro-8-methoxy-4-oxo-1,4-dihydro-3-quinolinecarboxyli...

1797982-51-41-Cyclopropyl-7-etho...
Compound Q&A

How should waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: 671820-52-3) be handled?

Waste containing Methyl 3-oxo-1,2,3,4-tetrahydro-6-quinoxalinecarboxylate (CAS: ...

671820-52-3Methyl 3-oxo-1,2,3,4...

Source Journal

Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
CiteScore: 5.5
Self-citation Rate: 10.3%
Articles per Year: 3036

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.