Copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling between cinnamic acids and aliphatic aldehydes

Literature Information

Publication Date 2018-10-08
DOI 10.1039/C8QO00927A
Impact Factor 5.281
Authors

Zaigang Luo, Xinxin Han, Yuyu Fang, Peng Liu, Chengtao Feng, Zhong Li, Xuemei Xu


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Abstract

A copper-catalyzed decarboxylative and oxidative decarbonylative cross-coupling of cinnamic acids with aliphatic aldehydes was achieved. The reaction undergoes subsequent decarbonylation, radical addition and decarboxylation processes with aliphatic aldehydes as the cheap and abundant alkyl radical source. This procedure offers a complementary approach to the convenient generation of alkyl-substituted E-alkenes.

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Organic Chemistry Frontiers

Organic Chemistry Frontiers
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Organic Chemistry Frontiers publishes high-quality research from across organic chemistry. Emphases are placed on studies that make significant contributions to the field of organic chemistry by reporting either new or significantly improved protocols or methodologies. Topics include, but are not limited to the following: Organic synthesis Development of synthetic methodologies Catalysis Natural products Functional organic materials Supramolecular and macromolecular chemistry Physical and computational organic chemistry

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