Quasi-monodisperse polymer libraries via flash column chromatography: correlating dispersity with glass transition
Literature Information
Publication Date
2018-12-28
DOI
10.1039/C8PY01603H
Impact Factor
5.582
Authors
Joris J. Haven, Tanja Junkers
View Original
Abstract
Quasi-monodisperse (Đ = 1.005–1.040) poly(methyl acrylate) (PMA) polymer libraries are obtained via flash column chromatography separation of polydisperse (Đ = 1.130) PMA made from reversible addition–fragmentation chain transfer (RAFT) polymerization. The limits of chromatographic polymer separation and analysis are discussed. In addition, the influence of dispersity on the thermal properties (glass transition) of the PMA library is investigated.
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Source Journal
Polymer Chemistry
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8.6
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