Cyclotrimerization of phenylacetylene catalyzed by a cobalt half-sandwich complex embedded in an engineered variant of transmembrane protein FhuA

Literature Information

Publication Date 2018-07-05
DOI 10.1039/C8OB01369A
Impact Factor 3.876
Authors

A. Thiel, D. F. Sauer, M. A. S. Mertens, T. Polen, H.-H. Chen, U. Schwaneberg, J. Okuda


View Original

Abstract

An (η5-cyclopentadienyl)cobalt(I) complex was covalently incorporated into an engineered variant of the transmembrane protein ferric hydroxamate uptake protein component: A, FhuA ΔCVFtev, using a thiol–ene reaction. A CD spectrum shows the structural integrity of the biohybrid catalyst. MALDI-TOF of the segment containing the anchoring site for the cobalt complex Cys545 confirmed successful conjugation. This biohybrid catalyst catalyzed the cyclotrimerization of phenylacetylene to give a mixture of regioisomeric 1,2,4- and 1,3,5-triphenylbenzene in aqueous medium.

Related Literature

A vibrational spectroscopic and computational study of gaseous protonated and alkali metal cationized G–C base pairs

Ruodi Cheng, Jonathan Martens, Travis D. Fridgen

2020-05-04 Paper

DOI: 10.1039/D0CP00069H

Universal crossed beam imaging studies of polyatomic reaction dynamics

Hongwei Li, Arthur G. Suits

2020-03-23 Perspective

DOI: 10.1039/D0CP00522C

Hierarchically organized materials with ordered mesopores: adsorption isotherm and adsorption-induced deformation from small-angle scattering

Lukas Ludescher, Roland Morak, Stephan Braxmeier, Florian Putz, Nicola Hüsing, Gudrun Reichenauer, Oskar Paris

2020-05-28 Paper

DOI: 10.1039/D0CP01026J

Mixed uranyl and neptunyl cation–cation interaction-driven clusters: structures, energetic stability, and nuclear quadrupole interactions

Paweł Tecmer, Frank Schindler, Aleksandra Leszczyk, Katharina Boguslawski

2020-05-02 Paper

DOI: 10.1039/D0CP01068E

Rapid and accurate molecular deprotonation energies from quantum alchemy

Guido Falk von Rudorff, O. Anatole von Lilienfeld

2019-12-19 Paper

DOI: 10.1039/C9CP06471K

A computational exploration of the 1D TiS2(en) nanostructure for lithium ion batteries

Chun-Hao Huang, Elise Y. Li

2020-03-31 Paper

DOI: 10.1039/C9CP04675E

Visualising electrochemical reaction layers: mediated vs. direct oxidation

Junling Ma, Minjun Yang, Christopher Batchelor-McAuley, Richard G. Compton

2020-05-22 Paper

DOI: 10.1039/D0CP01904F

FB-REDA: fragment-based decomposition analysis of the reorganization energy for organic semiconductors

Kun-Han Lin, Clémence Corminboeuf

2020-05-12 Paper

DOI: 10.1039/D0CP01722A

The eternal battle to combat global warming: (thio)urea as a CO2 wet scrubbing agent

Ala’a F. Eftaiha, Abdussalam K. Qaroush, Ahed W. Alsayyed, Feda’a Al-Qaisi, Fatima Alsoubani, Khaleel I. Assaf

2020-04-24 Paper

DOI: 10.1039/D0CP00629G

Reaction mechanism of the Me3AuPMe3–H2 plasma-enhanced ALD process

Michiel Van Daele, Matthew B. E. Griffiths, Matthias M. Minjauw, Seán T. Barry, Christophe Detavernier, Jolien Dendooven

2020-05-15 Paper

DOI: 10.1039/C9CP06855D

You might also like

Compound Q&A

What are the main uses of 4-Nitrophenyl phosphate disodium salt hexahydrate (CAS: 333338-18-4)?

4-Nitrophenyl phosphate disodium salt hexahydrate is primarily used as a substra...

333338-18-44-Nitrophenyl phosph...
Compound Q&A

What are the main uses of 2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4)?

2-(Trifluoromethyl)-1,3-oxazole-4-carboxylic Acid (CAS: 1060816-01-4) is widely ...

1060816-01-42-(Trifluoromethyl)-...
Compound Q&A

How should 2-Fluoro-4-biphenylcarboxylic acid (CAS: 137045-30-8) be stored?

2-Fluoro-4-biphenylcarboxylic acid should be stored in a cool, dry place at room...

137045-30-82-Fluoro-4-biphenylc...
Compound Q&A

What industries use Prednisolone-21-Carboxylic Acid (CAS: 61549-70-0)?

Prednisolone-21-Carboxylic Acid is primarily used in the pharmaceutical industry...

61549-70-0Prednisolone-21-Carb...
Compound Q&A

How should 4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) be stored?

4-(Hydrazinomethyl)-1,2,3-benzenetriol (CAS: 3614-72-0) should be stored in a co...

3614-72-04-(Hydrazinomethyl)-...
Compound Q&A

What industries use 4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8)?

4-Amino-1-methyl-1H-pyrazole-5-carboxylic acid hydrochloride (CAS: 92534-70-8) i...

92534-70-84-Amino-1-methyl-1H-...
Compound Q&A

What regulatory guidelines apply to dehydropachymic acid (CAS: 77012-31-8)?

Dehydropachymic acid (CAS: 77012-31-8) is regulated by various agencies. It fall...

77012-31-8Dehydropachymic acid
Compound Q&A

What is the market or research trend for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic acid (CAS: 898561-66-5)?

The market and research trends for 6-[(2,2-Dimethylpropanoyl)amino]nicotinic aci...

898561-66-56-[(2,2-Dimethylprop...
Compound Q&A

How should 1,10-Phenanthroline-2,9-dicarbaldehyde (CAS: 57709-62-3) be stored?

1,10-Phenanthroline-2,9-dicarbaldehyde should be stored in a cool, dry place awa...

57709-62-31,10-Phenanthroline-...
Compound Q&A

How is 5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate (CAS: 113952-21-9) typically synthesized?

5-Carbamoyl-11-oxo-10,11-dihydro-5H-dibenzo[b,f]azepin-10-yl acetate can be synt...

113952-21-95-Carbamoyl-11-oxo-1...

Source Journal

Organic & Biomolecular Chemistry

Organic & Biomolecular Chemistry
CiteScore: 3.4
Self-citation Rate: 10.3%
Articles per Year: 1041

Organic & Biomolecular Chemistry (OBC) publishes original and high impact research and reviews in organic chemistry. We welcome research that shows new or significantly improved protocols or methodologies in total synthesis, synthetic methodology or physical and theoretical organic chemistry as well as research that shows a significant advance in the organic chemistry or molecular design aspects of chemical biology, catalysis, supramolecular and macromolecular chemistry, theoretical chemistry, mechanism-oriented physical organic chemistry, medicinal chemistry or natural products. Articles published in the journal should report new work which makes a highly-significant impact in the field. Routine and incremental work is generally not suitable for publication in the journal. More details about key areas of our scope are below. In all cases authors should include in their article clear rationale for why their research has been carried out.

Recommended Compounds

Recommended Suppliers

Disclaimer
This page provides academic journal information for reference and research purposes only. We are not affiliated with any journal publishers and do not handle publication submissions. For publication-related inquiries, please contact the respective journal publishers directly.
If you notice any inaccuracies in the information displayed, please contact us at support@chemtradehub.com. We will promptly review and address your concerns.