Persulfate-promoted oxidative C–N bond coupling of quinoxalinones and NH-sulfoximines
Literature Information
Publication Date
2018-03-19
DOI
10.1039/C8OB00375K
Impact Factor
3.876
Authors
Ladawan Sumunnee, Chaleena Pimpasri, Medena Noikham, Sirilata Yotphan
View Original
Abstract
The persulfate-meditated oxidative C–N bond coupling of the C–H bond of quinoxalinones and the N–H bond of NH-sulfoximines is reported. The reaction proceeds smoothly under transition metal-free conditions and provides good to excellent yields of sulfoximidoyl-functionalized quinoxalinone products under mild conditions. The optimized conditions were found to be suitable for a range of sulfoximine and quinoxalinone substrates. This reaction offers a new and convenient strategy to directly install the sulfoximine moiety into the C3 position of quinoxalinone.
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Source Journal
Organic & Biomolecular Chemistry
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