Pyro-catalytic hydrogen evolution by Ba0.7Sr0.3TiO3 nanoparticles: harvesting cold–hot alternation energy near room-temperature
Literature Information
Xiaoli Xu, Lingbo Xiao, Yanmin Jia, Zheng Wu, Feifei Wang, Yaojin Wang, Neale O. Haugen, Haitao Huang
Photocatalytic hydrogen evolution, as an environmental-friendly, energy-saving and simple process, has been widely reported. However, there are some important factors that prohibit practical application of photocatalytic hydrogen production, including the low efficiency of solar energy utilization, and the lack of response in the dark. Temperature fluctuation is a very common phenomenon in our daily life, which is rarely reported for use for hydrogen production. Here we demonstrate direct hydrogen evolution through the harvesting of cold–hot 298–323 K (25–50 °C) alternation energy by using pyroelectric nanomaterial Ba0.7Sr0.3TiO3 (BST). The yield of hydrogen achieved was 46.89 μmol per gram of catalyst after 36 thermal cycles and the rate of hydrogen generation was up to 1.30 μmol g−1 per thermal cycle. The minimum of the conduction band of BST is more negative than the conduction band level of H+/H2, enabling the reduction of water to form hydrogen. This efficient and eco-friendly pyro-catalytic method provides a promising future for hydrogen evolution utilizing natural cold–hot temperature fluctuation energy.
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Energy & Environmental Science

Energy & Environmental Science is an international journal dedicated to publishing exceptionally important and high quality, agenda-setting research tackling the key global and societal challenges of ensuring the provision of energy and protecting our environment for the future. The scope is intentionally broad and the journal recognises the complexity of issues and challenges relating to energy conversion and storage, alternative fuel technologies and environmental science. For work to be published it must be linked to the energy-environment nexus and be of significant general interest to our community-spanning readership. All scales of studies and analysis, from impactful fundamental advances, to interdisciplinary research across the (bio)chemical, (bio/geo)physical sciences and chemical engineering disciplines are welcomed. Topics include, but are not limited to, the following: Solar energy conversion and photovoltaics Solar fuels and artificial photosynthesis Fuel cells Hydrogen storage and (bio) hydrogen production Materials for energy systems Capture, storage and fate of CO2, including chemicals and fuels from CO2 Catalysis for a variety of feedstocks (for example, oil, gas, coal, biomass and synthesis gas) Biofuels and biorefineries Materials in extreme environments Environmental impacts of energy technologies Global atmospheric chemistry and climate change as related to energy systems Water-energy nexus Energy systems and networks Globally applicable principles of energy policy and techno-economics











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