What's in a name? ‘Coinage-metal’ non-covalent bonds and their definition
Literature Information
Anthony C. Legon, Nicholas R. Walker
Many complexes of the type B⋯MX, (where B is a Lewis base such as H2, N2, ethyne, ethene, cyclopropane, H2O, H2S, PH3, or NH3, M is a coinage-metal atom Cu, Ag or Au, and X is a halogen atom) have now been characterised in the gas phase through their rotational spectra. It is pointed out that, for a given B, such complexes have angular geometries that are isomorphous with those of their hydrogen- and halogen-bonded counterparts B⋯HX and B⋯XY, respectively. Since the MX are, like the B, HX and XY referred to, closed-shell molecules, the complexes B⋯MX also involve a non-covalent bond. Therefore, the name ‘coinage-metal’ bond is suggested for the non-covalent interaction in B⋯MX, by analogy with hydrogen and halogen bonds. A generalised definition that covers all non-covalent bonds is also presented.
Related Literature
Functionalization of metal nanoclusters for biomedical applications
Nirmal Goswami, Huang-Hao Yang, Jianping Xie
DOI: 10.1039/C6AN00773B
An intramolecular charge transfer and excited state intramolecular proton transfer based fluorescent probe for highly selective detection and imaging of formaldehyde in living cells
Wen Chen, Mei Yang, Na Luo, Fenglin Wang, Ru-Qin Yu, Jian-Hui Jiang
DOI: 10.1039/C9AN01778J
Styrylpyridine salts-based red emissive two-photon turn-on probe for imaging the plasma membrane in living cells and tissues
Lifang Guo, Ruoyao Zhang, Yuming Sun, Minggang Tian, Ge Zhang, Ruiqing Feng, Xuechen Li, Xiaoqiang Yu, Xiuquan He
DOI: 10.1039/C6AN00147E
Recent advances in inorganic materials for LDI-MS analysis of small molecules
C. Y. Shi, C. H. Deng
DOI: 10.1039/C6AN00220J
Semi-automatic instrumentation for nucleic acid extraction and purification to quantify pathogens on surfaces
Won-Nyoung Lee, Hyun Jin Yoo, Kim Huyen Nguyen, Changyoon Baek, Junhong Min
DOI: 10.1039/C9AN00896A
Electrochemical sensors for rapid diagnosis of pathogens in real time
Olja Simoska, Keith J. Stevenson
DOI: 10.1039/C9AN01747J
Addressing the practicalities of anodic stripping voltammetry for heavy metal detection: a tutorial review
Julie V. Macpherson
DOI: 10.1039/C9AN01437C
Smartphone spectrometer for colorimetric biosensing
Xiaohu Liu, Peng Chen, Nhung Thi Tran, Jinling Zhang, Wei Sheng Chia, Bo Liedberg
DOI: 10.1039/C5AN02508G
Screening of DNA G-quadruplex stabilizing ligands by nano differential scanning fluorimetry
Bruno Pagano, Nunzia Iaccarino, Anna Di Porzio, Antonio Randazzo, Jussara Amato
DOI: 10.1039/C9AN01463B
You might also like
What precautions should be taken when handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3)?
When handling 4-(2-Furylmethyl)thiomorpholine 1,1-dioxide (CAS: 79206-94-3), it ...
What precautions should be taken when handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9)?
When handling 4-Chloro-N-[2-(4-morpholinyl)ethyl]benzamide (CAS: 71320-77-9), it...
How should waste containing 2-[2-(2-Methoxyethoxy)ethoxy]ethyl 4-methylbenzenesulfonate (CAS: 62921-74-8) be handled?
Waste containing this compound (CAS: 62921-74-8) should be handled according to ...
How should waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate be handled?
Waste containing (S)-Methyl 2-amino-3-cyclohexylpropanoate should be collected i...
How is 5-({4-[(2S,4R)-4-Hydroxy-2-methyltetrahydro-2H-pyran-4-yl]-2-thienyl}sulfanyl)-1-methyl-1,3-dihydro-2H-indol-2-one (CAS: 166882-70-8) typically synthesized?
This compound can be synthesized using a multi-step process involving the conjug...
Are there alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid (CAS: 7312-27-8) in synthesis?
There are several alternatives to (2E)-3-(3,4-Dichlorophenyl)acrylic acid in syn...
How should Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84-9) be stored?
Ethyl 6-(2-nitrophenyl)imidazo[2,1-b][1,3]thiazole-3-carboxylate (CAS: 925437-84...
How should waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) be handled?
Waste containing 2-(1,3-Thiazol-2-yl)ethanamine (CAS: 18453-07-1) should be coll...
How is Methyl 5-iodo-2-methylbenzoate (CAS: 103440-54-6) typically synthesized?
Methyl 5-iodo-2-methylbenzoate can be synthesized through the iodination of meth...
How is 5-Chloro[1,2,4]triazolo[1,5-a]pyridine (CAS: 1427399-34-5) typically synthesized?
5-Chloro[1,2,4]triazolo[1,5-a]pyridine is commonly synthesized via the condensat...
Source Journal
Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics (PCCP) is an international journal co-owned by 19 physical chemistry and physics societies from around the world. This journal publishes original, cutting-edge research in physical chemistry, chemical physics and biophysical chemistry. To be suitable for publication in PCCP, articles must include significant innovation and/or insight into physical chemistry; this is the most important criterion that reviewers and Editors will judge against when evaluating submissions. The journal has a broad scope and welcomes contributions spanning experiment, theory, computation and data science. Topical coverage includes spectroscopy, dynamics, kinetics, statistical mechanics, thermodynamics, electrochemistry, catalysis, surface science, quantum mechanics, quantum computing and machine learning. Interdisciplinary research areas such as polymers and soft matter, materials, nanoscience, energy, surfaces/interfaces, and biophysical chemistry are welcomed if they demonstrate significant innovation and/or insight into physical chemistry. Joined experimental/theoretical studies are particularly appreciated when complementary and based on up-to-date approaches.










![N-[(Benzyloxy)carbonyl]serine structure N-[(Benzyloxy)carbonyl]serine structure](https://static.chemtradehub.com/structs/276/2768-56-1-77f7.webp)



