Reductive defluorination of graphite monofluoride by weak, non-nucleophilic reductants reveals low-lying electron-accepting sites

Literature Information

Publication Date 2018-05-02
DOI 10.1039/C8CP00384J
Impact Factor 3.676
Authors

Yijun Liu, Benjamin W. Noffke, Xinfeng Gao, Yaroslav Lozovyj, Yongzhu Fu, Krishnan Raghavachari, Allen R. Siedle, Liang-shi Li


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Abstract

Graphite monofluoride (GF) can undergo reductive defluorination in the presence of weak, non-nucleophilic reductants. This leads to a new approach to GF–polyaniline composites as cathode materials for significantly improving the discharge capacity of primary lithium batteries. We postulate that the reduction is mediated by residual π-bonds in GF.

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Physical Chemistry Chemical Physics

Physical Chemistry Chemical Physics
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